Transparent, superparamagnetic KxICoyII[FeIII(CN)6]1 -: Silica nanocomposites with tunable photomagnetism

被引：145

作者：

Moore, JG

Lochner, EJ

Ramsey, C

Dalal, NS

Stiegman, AE ^{[1
]}

机构：

[1] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

[2] Florida State Univ, MARTECH, Tallahassee, FL 32306 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 24期

关键词：

cobalt; iron; magnetic properties; nanostructures; sol-gel processes;

D O I：

10.1002/anie.200250409

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Moldable magnetism: Tunable photomagnetism is exhibited by homogeneous, optically transparent, moldable silica xerogel nanocomposites containing the ferromagnetic Prussian blue analogue KxCoyII[FeIII (CN)6]z. These materials also show a blue-shifted intervalence charge-transfer band and superparamagnetic behavior. The picture shows the temperature dependence of the field-cooled (FC) and zero-field-cooled (ZFC) dc magnetization μ of a xerogel sample (inset).

引用

页码：2741 / 2743

页数：3

共 18 条

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