Role of chlorocarbon oligomers in the room-temperature heterogeneous catalytic fluorination of hydrochlorocarbons to hydrochlorofluorocarbons

被引：10

作者：

Bendada, A

Bonniface, DW

McMonagle, F

Marshall, R

Shortman, C

Spence, RR

Thomson, J

Webb, G

Winfield, JM

Winterton, N

机构：

[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,LANARK,SCOTLAND

[2] ICI CHEM & POLYMERS LTD,RES & TECHNOL DEPT,RUNCORN WA7 4QD,CHESHIRE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 16期

关键词：

D O I：

10.1039/cc9960001947

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Radiotracer [F-18] and [Cl-36] experiments demonstrate the deposition of oligomeric chlorocarbon species on fluorinated metal oxides and trapping of hydrochlorocarbon monomers, both without loss of surface fluoride lability, thus accounting for the unusual room-temperature heterogeneous catalytic fluorination of CH3CCl3 and related species by anhydrous HF.

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页码：1947 / 1948

页数：2

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