A novel coordination mode for pentalene in trinuclear chromium complexes

被引：9

作者：

Jones, SC ^{[1
]}

Hascall, T ^{[1
]}

Norquist, AJ ^{[1
]}

O'Hare, D ^{[1
]}

机构：

[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 24期

关键词：

D O I：

10.1021/ic0350887

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first chromium pentalene complexes have been characterized; in these the ligand displays a hitherto-unknown bonding mode whereby a dimeric [Cr(CP*)](2)(mu-OR) unit is bound (mu:eta(2):eta(2))- to one face, and Cp*Cr is bound eta(5)- to the other. The magnetic properties of these compounds can be understood as the superposition of those of a chromocene and an antiferromagnetically coupled Cr-Cr bonded unit.

引用

页码：7707 / 7709

页数：3

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