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Photo-Degradation of Methelyne Blue over V2O5-TiO2 Nano-Porous Layers Synthesized by Micro Arc Oxidation
被引:63
作者:
Bayati, M. R.
[3
]
Golestani-Fard, F.
[3
]
Moshfegh, A. Z.
[1
,2
]
机构:
[1] Sharif Univ Technol, Dept Phys, Tehran, Iran
[2] Sharif Univ Technol, Inst Nanosci & Nanotechnol, Tehran, Iran
[3] Iran Univ Sci & Technol, Dept Met & Mat Engn, Tehran, Iran
关键词:
Micro arc oxidation;
Titanium oxide;
Vanadium oxide;
Catalysis;
PLASMA ELECTROLYTIC OXIDATION;
DOPED TIO2 NANOPARTICLES;
PHOTOCATALYTIC ACTIVITY;
METHYLENE-BLUE;
THIN-FILM;
TITANIUM;
DECOMPOSITION;
DEGRADATION;
COATINGS;
MECHANISM;
D O I:
10.1007/s10562-009-0231-5
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070305 [高分子化学与物理];
摘要:
V2O5-TiO2 porous layers were synthesized via micro-arc oxidation for the first time. The effect of the applied voltage on morphology, composition, and photo-activity of the layers was investigated. The layers, which consisted of anatase, rutile, and vanadium pentoxide phases, revealed an enhanced photo-activity. About 93% of methylene blue solution was degraded on the synthesized layers after 120 min UV-irradiation with a reaction rate constant of k = 0.0228 min(-1). The band gap energies of the vanadia-titania and pure titania layers were calculated as 2.56 and 3.39 eV, respectively.
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页码:162 / 168
页数:7
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