Photo-Degradation of Methelyne Blue over V2O5-TiO2 Nano-Porous Layers Synthesized by Micro Arc Oxidation

被引:63
作者
Bayati, M. R. [3 ]
Golestani-Fard, F. [3 ]
Moshfegh, A. Z. [1 ,2 ]
机构
[1] Sharif Univ Technol, Dept Phys, Tehran, Iran
[2] Sharif Univ Technol, Inst Nanosci & Nanotechnol, Tehran, Iran
[3] Iran Univ Sci & Technol, Dept Met & Mat Engn, Tehran, Iran
关键词
Micro arc oxidation; Titanium oxide; Vanadium oxide; Catalysis; PLASMA ELECTROLYTIC OXIDATION; DOPED TIO2 NANOPARTICLES; PHOTOCATALYTIC ACTIVITY; METHYLENE-BLUE; THIN-FILM; TITANIUM; DECOMPOSITION; DEGRADATION; COATINGS; MECHANISM;
D O I
10.1007/s10562-009-0231-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
V2O5-TiO2 porous layers were synthesized via micro-arc oxidation for the first time. The effect of the applied voltage on morphology, composition, and photo-activity of the layers was investigated. The layers, which consisted of anatase, rutile, and vanadium pentoxide phases, revealed an enhanced photo-activity. About 93% of methylene blue solution was degraded on the synthesized layers after 120 min UV-irradiation with a reaction rate constant of k = 0.0228 min(-1). The band gap energies of the vanadia-titania and pure titania layers were calculated as 2.56 and 3.39 eV, respectively.
引用
收藏
页码:162 / 168
页数:7
相关论文
共 50 条
[1]
Feasibility study of photoelectrochemical degradation of methylene blue with three-dimensional electrode-photocatalytic reactor [J].
An, TC ;
Zhu, XH ;
Xiong, Y .
CHEMOSPHERE, 2002, 46 (06) :897-903
[2]
Anionic (IO3-) non-metal doped TiO2 nanoparticles for the photocatalytic degradation of hazardous pollutant in water [J].
Anandan, S. ;
Kathiravan, K. ;
Murugesan, V. ;
Ikuma, Y. .
CATALYSIS COMMUNICATIONS, 2009, 10 (06) :1014-1019
[3]
Gas-phase selective oxidation of chloro- and methoxy-substituted toluenes on TiO2-Sepiolite supported vanadium oxides [J].
Bautista, F. M. ;
Luna, D. ;
Luque, J. ;
Marinas, J. M. ;
Sanchez-Royo, J. F. .
APPLIED CATALYSIS A-GENERAL, 2009, 352 (1-2) :251-258
[4]
Photocatalytic properties of nanocrystalline TiO2 thin film with Ag additions [J].
Chang, CC ;
Lin, CK ;
Chan, CC ;
Hsu, CS ;
Chen, CY .
THIN SOLID FILMS, 2006, 494 (1-2) :274-278
[5]
Visible light induced photocatalytic degradation of organic pollutants [J].
Chatterjee, D ;
Dasgupta, S .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2005, 6 (2-3) :186-205
[6]
ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+
[7]
Photo-catalytic degradation of methyl orange and formaldehyde by Ag/InVO4-TiO2 thin films under visible-light irradiation [J].
Ge, Lei ;
Xu, Mingxia ;
Fang, Haibo .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 258 (1-2) :68-76
[8]
A novel method for preparing v-doped titanium dioxide thin film photocatalysts with high photocatalytic activity under visible light irradiation [J].
Gu, De-En ;
Yang, Bang-Chao ;
Hu, Yong-Da .
CATALYSIS LETTERS, 2007, 118 (3-4) :254-259
[9]
Electrolytic plasma technology: Science and engineering - An overview [J].
Gupta, P. ;
Tenhundfeld, G. ;
Daigle, E. O. ;
Ryabkov, D. .
SURFACE & COATINGS TECHNOLOGY, 2007, 201 (21) :8746-8760
[10]
Charge Transfer in Photocatalytic Systems: V and Mo Doped TiO2/Ti Electrodes [J].
Haber, Jerzy ;
Nowak, Pawel ;
Zurek, Pawel .
CATALYSIS LETTERS, 2008, 126 (1-2) :43-48