A dihydroxo-bridged Fe(II)-Fe(III) complex: A new member of the diiron diamond core family

被引:19
作者
Egdal, RK
Hazell, A
Larsen, FB
McKenzie, CJ
Scarrow, RC [1 ]
机构
[1] Univ So Denmark, Dept Chem, DK-5230 Odense M, Denmark
[2] Aarhus Univ, Dept Chem, DK-8000 Aarhus, Denmark
[3] Haverford Coll, Dept Chem, Haverford, PA 19041 USA
关键词
D O I
10.1021/ja027219t
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first structurally characterized Fe(II)-Fe(III) complex containing a M2(μ-OH)2 diamond core is a Robin and Day class II mixed-valence complex. Copyright © 2003 American Chemical Society.
引用
收藏
页码:32 / 33
页数:2
相关论文
共 19 条
[1]   Influence of extrinsic factors on electron transfer in a mixed-valence Fe2+/Fe3+ complex:: Experimental results and theoretical considerations [J].
Achim, C ;
Bominaar, EL ;
Staples, RJ ;
Münck, E ;
Holm, RH .
INORGANIC CHEMISTRY, 2001, 40 (17) :4389-4403
[2]  
Allen F.H., 1993, CHEM AUTOMAT NEWS, V8, P31
[3]  
Bunker G., 1991, X-ray Absorption Fine Structure, P751
[4]   μ-Oxo-bis{chloro[N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)ethane-1,2-diamine]iron(III)} diperchlorate 0.751-hydrate [J].
Egdal, RK ;
Hazell, A ;
McKenzie, CJ .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 :M10-M12
[5]   PROPERTIES AND REACTIVITY OF UNUSUAL DIIRON COMPLEXES OF A LINEAR TETRADENTATE LIGAND - CRYSTAL-STRUCTURES OF DIIRON-(II) AND DIIRON-(III) COMPLEXES [J].
HAZELL, R ;
JENSEN, KB ;
MCKENZIE, CJ ;
TOFTLUND, H .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (05) :707-717
[6]   Crystal structure of a synthetic high-valent complex with an Fe2(μ-O)2 diamond core.: Implications for the core structures of methane monooxygenase intermediate Q and ribonucleotide reductase intermediate X [J].
Hsu, HF ;
Dong, YH ;
Shu, LJ ;
Young, VG ;
Que, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (22) :5230-5237
[7]   Indication of a hydrogen-atom abstraction reaction relevant to a mechanistic proposal for the oxygen-evolving complex of photosystem II [J].
Jensen, KB ;
McKenzie, CJ ;
Pedersen, JZ .
INORGANIC CHEMISTRY, 2001, 40 (20) :5066-+
[8]   Structural and spectroscopic studies of valence-delocalized diiron(III) complexes supported by carboxylate-only bridging ligands [J].
Lee, D ;
DuBois, JL ;
Pierce, B ;
Hedman, B ;
Hodgson, KO ;
Hendrich, MP ;
Lippard, SJ .
INORGANIC CHEMISTRY, 2002, 41 (12) :3172-3182
[9]   Model for the cofactor formation reaction of E-coli ribonucleotide reductase.: From a diiron(II) precursor to an FeIIIFeIV species via a peroxo intermediate [J].
MacMurdo, VL ;
Zheng, H ;
Que, L .
INORGANIC CHEMISTRY, 2000, 39 (11) :2254-+
[10]   MOLECULAR-STRUCTURE AND MAGNETIC-PROPERTIES OF MU-DIHYDROXO-BIS[4-DIMETHYLAMINO-2,6-PYRIDINE-DICARBOXYLATOAQUOIRON(III)] DIHYDRATE, [(CH3)2NC7H2NO4(H2O)FEOH]2.2H2O [J].
OU, CC ;
LALANCETTE, RA ;
POTENZA, JA ;
SCHUGAR, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (07) :2053-2057