Taxonomy of periodic nets and the design of materials

被引:209
作者
Delgado-Friedrichs, Olaf
O'Keeffe, Michael [1 ]
Yaghi, Omar M.
机构
[1] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA
[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
[3] Univ Calif Los Angeles, Ctr Reticular Chem, Los Angeles, CA 90095 USA
关键词
METAL-ORGANIC-FRAMEWORKS; 3-PERIODIC NETS; RETICULAR CHEMISTRY; BUILDING-BLOCKS; MINIMAL NETS; TILINGS; IMIDAZOLATE; TOPOLOGY; CRYSTALS;
D O I
10.1039/b615006c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The concept of a natural tiling for a periodic net is introduced and used to derive a transitivity associated with the structure. It is accordingly shown that the transitivity provides a useful method of classifying polyhedra and nets. For design of materials to serve as targets for synthesis, structures with one kind of edge ( edge transitive) are particularly important. Edge-transitive polyhedra, layers and 3-periodic nets are then described. Some other nets of special importance in crystal chemistry are also identified.
引用
收藏
页码:1035 / 1043
页数:9
相关论文
共 33 条
[1]  
Baerlocher C., 2001, ATLAS ZEOLITE FRAMEW, V5th, P398
[2]   Glorious uncertainty - challenges for network design [J].
Batten, SR .
JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (08) :2475-2479
[3]   MINIMAL NETS [J].
BEUKEMANN, A ;
KLEE, WE .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1992, 201 (1-2) :37-51
[4]  
BLATOV VA, IN PRESS
[5]   Three-periodic nets and tilings: minimal nets [J].
Bonneau, C ;
Delgado-Friedrichs, O ;
O'Keeffe, M ;
Yaghi, OM .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2004, 60 :517-520
[6]   PARAMETERS FOR FRAMEWORKS AND SPACE FILLING POLYHEDRA [J].
BRUNNER, GO .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1981, 156 (3-4) :295-303
[7]   A route to high surface area, porosity and inclusion of large molecules in crystals [J].
Chae, HK ;
Siberio-Pérez, DY ;
Kim, J ;
Go, Y ;
Eddaoudi, M ;
Matzger, AJ ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 2004, 427 (6974) :523-527
[8]   Design of frameworks with mixed triangular and octahedral building blocks exemplified by the structure of [Zn4O(TCA)2] having the pyrite topology [J].
Chae, HK ;
Kim, J ;
Friedrichs, OD ;
O'Keefe, M ;
Yaghi, OM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (33) :3907-3909
[9]   On a simple tiling of Deza and Shtogrin [J].
Delgado-Friedrichs, O ;
O'Keeffe, M .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2006, 62 :228-229
[10]   What do we know about three-periodic nets? [J].
Delgado-Friedrichs, O ;
Foster, MD ;
O'Keeffe, M ;
Proserpio, DM ;
Treacy, MMJ ;
Yaghi, OM .
JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (08) :2533-2554