Surface-initiated ring-opening metathesis polymerization on Si/SiO2

被引：155

作者：

Kim, NY

Jeon, NL

Choi, IS

Takami, S

Harada, Y

Finnie, KR

Girolami, GS

Nuzzo, RG

Whitesides, GM

Laibinis, PE

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

[2] Univ Illinois, Seitz Mat Res Lab, Urbana, IL 61801 USA

[3] MIT, Dept Chem, Cambridge, MA 02139 USA

[4] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

[5] MIT, Dept Chem Engn, Cambridge, MA 02139 USA

来源：

MACROMOLECULES | 2000年 / 33卷 / 08期

关键词：

D O I：

10.1021/ma000046c

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A method for growing thin polymer films from the surface of a silicon wafer bearing a native oxide (Si/SiO2) by ring-opening metathesis polymerization (ROMP) is described. The norbornene-derived polymer films were prepared with a wide range of thicknesses up to 1 μm and with a control over the chemical composition of the film perpendicular to the surface. It was observed that surface-initiated polymerization using ROMP can be used to grow covalently attached norbornene-based polymer films from an oxide surface by solution phase procedures.

引用

页码：2793 / 2795

页数：3

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