Critical behavior of gelation probed by the dynamics of latex spheres

被引:24
作者
Fadda, GC
Lairez, D [1 ]
Pelta, J
机构
[1] CEA Saclay, CNRS, Leon Brillouin Lab, F-91191 Gif Sur Yvette, France
[2] Univ Cergy Pontoise, ERRMECE, F-95302 Cergy Pontoise, France
来源
PHYSICAL REVIEW E | 2001年 / 63卷 / 06期
关键词
D O I
10.1103/PhysRevE.63.061405
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We report a quasielastic light scattering study of the dynamics of large latex probe particles (R = 225 nm) in gelatin solution undergoing gelation. We show that by focusing on the short-time and long-time behavior of the autocorrelation function, it is possible to simply interpret out data in terms of the divergence of the viscosity and emergence of the shear elastic modulus near the gel point. Our crude analysis allows us to grasp the critical behavior of gelation and to obtain the two critical exponents of the transport properties.
引用
收藏
页码:1 / 061405
页数:9
相关论文
共 31 条
[1]  
ADAM D, 1996, PHYSICAL PROPERTIES, P87
[2]   DYNAMICAL STUDIES OF POLYMERIC CLUSTER SOLUTIONS OBTAINED NEAR THE GELATION THRESHOLD - GLASSLIKE BEHAVIOR [J].
ADAM, M ;
DELSANTI, M ;
MUNCH, JP ;
DURAND, D .
PHYSICAL REVIEW LETTERS, 1988, 61 (06) :706-709
[3]  
Bastide J., 1996, PHYS PROPERTIES POLY, P143
[4]   DIFFUSION OF POLYSTYRENE LATEX SPHERES IN POLYMER-SOLUTIONS STUDIED BY DYNAMIC LIGHT-SCATTERING [J].
BROWN, W ;
RYMDEN, R .
MACROMOLECULES, 1986, 19 (12) :2942-2952
[5]   INTERACTION OF (CARBOXYMETHYL)CELLULOSE WITH LATEX SPHERES STUDIED BY DYNAMIC LIGHT-SCATTERING [J].
BROWN, W ;
RYMDEN, R .
MACROMOLECULES, 1987, 20 (11) :2867-2873
[6]   DIFFUSION OF DEXTRAN IN AQUEOUS (HYDROXYPROPYL)CELLULOSE [J].
BU, Z ;
RUSSO, PS .
MACROMOLECULES, 1994, 27 (05) :1187-1194
[7]  
CARNINS B, 1994, LANGMUIR, V10, P4053
[8]   DYNAMICS OF LIVING POLYMERS AND FLEXIBLE SURFACTANT MICELLES - SCALING LAWS FOR DILUTION [J].
CATES, ME .
JOURNAL DE PHYSIQUE, 1988, 49 (09) :1593-1600
[9]  
Chu B., 1991, LASER LIGHT SCATTERI, V2nd
[10]  
De Gennes P.G., 1979, SCALING CONCEPT POLY