Quasi-nature catalysis: conjugated addition of unsaturated carbonyl compounds with aryl and vinyltin reagents catalyzed by rhodium in air and water

被引:40
作者
Venkatraman, S [1 ]
Meng, Y [1 ]
Li, CJ [1 ]
机构
[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0040-4039(01)00761-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In air and water, trialkylphenyl- or trialkylvinylstannanes react with alpha,beta -unsaturated esters and ketones to give the corresponding conjugated addition products in high yields in the presence of a rhodium catalyst. (C) 2001 Published by Elsevier Science Ltd.
引用
收藏
页码:4459 / 4462
页数:4
相关论文
共 52 条
[1]  
[Anonymous], 1994, ORGANOMETALLICS SYNT
[2]  
[Anonymous], 1994, Org. React
[3]  
BRISTOW GS, 1984, ALDRICHIM ACTA, V17, P75
[4]   CROSSED ALDOL TYPE CONDENSATION-REACTIONS IN AQUEOUS-MEDIA [J].
CHAN, TH ;
LI, CJ ;
WEI, ZY .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (06) :505-507
[5]   A NEW CATALYTIC ACTIVITY OF ANTIMONY(III) CHLORIDE IN PALLADIUM(0)-CATALYZED CONJUGATE ADDITION OF AROMATICS TO ALPHA,BETA-UNSATURATED KETONES AND ALDEHYDES WITH SODIUM TETRAPHENYLBORATE AND ARYLBORONIC ACIDS [J].
CHO, CS ;
MOTOFUSA, S ;
OHE, K ;
UEMURA, S .
JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (04) :883-888
[6]  
CURRAN DP, 1991, SYNLETT, P107
[7]  
Davies A.G., 1997, ORGANOTIN CHEM
[8]  
GIESE B, 1983, ANGEW CHEM INT EDIT, V22, P622, DOI 10.1002/anie.198306221
[9]  
GIESE B, 1986, RADICALS ORGANI SYNT
[10]  
GIOVANNINI R, 1995, SYNLETT, P973