11% Efficient Ternary Organic Solar Cells with High Composition Tolerance via Integrated Near-IR Sensitization and Interface Engineering

被引:242
作者
Nian, Li [1 ]
Gao, Ke [1 ]
Liu, Feng [2 ,3 ]
Kan, Yuanyuan [1 ]
Jiang, Xiaofang [1 ]
Liu, Linlin [1 ]
Xie, Zengqi [1 ]
Peng, Xiaobin [1 ]
Russell, Thomas P. [3 ,4 ]
Ma, Yuguang [1 ]
机构
[1] South China Univ Technol, Inst Polymer Optoelect Mat & Devices, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
[2] Shanghai Jiao Tong Univ, Dept Phys & Astron, Shanghai 200240, Peoples R China
[3] Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA
[4] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
基金
对外科技合作项目(国际科技项目); 中国国家自然科学基金;
关键词
composition tolerance; high efficiency; near-IR sensitization; photoconductive cathode interlayers; ternary organic solar cells; OPEN-CIRCUIT VOLTAGE; POWER CONVERSION EFFICIENCY; CONJUGATED POLYMER; THERMAL-STABILITY; BANDGAP POLYMER; ENERGY-TRANSFER; SMALL MOLECULES; FULLERENE; BISADDUCT; ACCEPTOR;
D O I
10.1002/adma.201602834
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly efficient electron extraction is achieved by using a photoconductive cathode interlayer in inverted ternary organic solar cells (OSCs) where a near-IR absorbing porphyrin molecule is used as the sensitizer. The OSCs show improved device performance when the ratio of the two donors varies in a large region and a maximum power conversion efficiency up to 11.03% is demonstrated.
引用
收藏
页码:8184 / 8190
页数:7
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