Synthesis of controlled structure water-soluble diblock copolymers via oxyanionic polymerization

被引:132
作者
Vamvakaki, M [1 ]
Billingham, NC [1 ]
Armes, SP [1 ]
机构
[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
关键词
D O I
10.1021/ma981779o
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Monohydroxy-capped poly(alkylene oxide)s were used as macroinitiators for the polymerization of several tertiary amine methacrylates namely, DMAEMA, DEAEMA, 2-(N-morpholino) ethyl methacrylate (MEMA), and 2-(diisopropylamino) ethyl methacrylate (DPAEMA). High yields and good control over copolymer molecular weight were obtained for the polymerization of all four tertiary amine methacrylate monomers.
引用
收藏
页码:2088 / 2090
页数:3
相关论文
共 33 条
  • [1] Neutron reflectivity of an adsorbed water-soluble block copolymer: A surface transition to micelle-like aggregates at the air/water interface
    An, SW
    Su, TJ
    Thomas, RK
    Baines, FL
    Billingham, NC
    Armes, SP
    Penfold, J
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (02): : 387 - 393
  • [2] Use of block copolymer stabilizers for the dispersion polymerization of styrene in alcoholic media
    Baines, FL
    Dionisio, S
    Billingham, NC
    Armes, SP
    [J]. MACROMOLECULES, 1996, 29 (09) : 3096 - 3102
  • [3] Synthesis and solution properties of water-soluble hydrophilic-hydrophobic block copolymers
    Baines, FL
    Billingham, NC
    Armes, SP
    [J]. MACROMOLECULES, 1996, 29 (10) : 3416 - 3420
  • [4] Micellization of poly(2-(dimethylamino)ethyl methacrylate-block-methyl methacrylate) copolymers in aqueous solution
    Baines, FL
    Armes, SP
    Billingham, NC
    Tuzar, Z
    [J]. MACROMOLECULES, 1996, 29 (25) : 8151 - 8159
  • [5] Novel family of thermogelling materials via C-C bonding between poly(acrylic acid) and poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide)
    Bromberg, L
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (11) : 1956 - 1963
  • [6] Synthesis of shell cross-linked micelles with tunable hydrophilic/hydrophobic cores
    Bütün, V
    Billingham, NC
    Armes, SP
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (46) : 12135 - 12136
  • [7] Unusual aggregation behavior of a novel tertiary amine methacrylate-based diblock copolymer: Formation of micelles and reverse micelles in aqueous solution
    Butun, V
    Billingham, NC
    Armes, SP
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (45) : 11818 - 11819
  • [8] Selective betainisation of tertiary amine methacrylate block copolymers
    Butun, V
    Bennett, CE
    Vamvakaki, M
    Lowe, AB
    Billingham, NC
    Armes, SP
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (09) : 1693 - 1695
  • [9] BUTUN V, 1997, CHEM COMMUN, P697
  • [10] BUTUN V, UNPUB