LC acrylic monomers incorporating monothiobenzoate unit

被引:7
作者
Caillier, L [1 ]
Guittard, F [1 ]
de Givenchy, ET [1 ]
Geribaldi, S [1 ]
机构
[1] Univ Nice Sophia Antipolis, Fac Sci, Lab Chim Mat Organ & Met, F-06108 Nice, France
关键词
acrylic; monophenyl; perfluoro; smectic; thiobenzoate;
D O I
10.1080/15421400590955154
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The development of LC monophenyl unit is of a great interest for reach low cost LC materials. The aim of this work was to demonstrate the possibility to obtain monomer incorporating single phenyl unit for LC field. We report the synthesis and the characterization of acrylic monomers in fluorinated series which differ by the lengthening of the hydrocarbon spacer linking the acrylic part to the "mesogenic" core. LC behaviour was determined by DSC and POM apparatus. The increasing of the length of this hydrocarbon spacer dramatically decreases the span of the mesophase of type smectic. For a long spacer no mesomorphism is observed.
引用
收藏
页码:1315 / +
页数:11
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