Observation of secondary 2-butene ozonide in the ozonation of trans-2-butene in the gas phase

被引：22

作者：

Fajgar, R

Vitek, J

Haas, Y

Pola, J

机构：

[1] ACAD SCI CZECH REPUBL,INST CHEM PROC FUNDAMENTALS,CR-16502 PRAGUE,CZECH REPUBLIC

[2] HEBREW UNIV JERUSALEM,DEPT PHYS CHEM,IL-91904 JERUSALEM,ISRAEL

[3] HEBREW UNIV JERUSALEM,FARKAS CTR LIGHT IND PROC,IL-91904 JERUSALEM,ISRAEL

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 19期

关键词：

D O I：

10.1016/0040-4039(96)00554-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

GC/MS detection of secondary 2-butene ozonide in the gas-phase ozonation of trans-2-butene provides the first conclusive evidence on the feasibility of the combination of Criegee intermediate with parent carbonyl compound, which is not facilitated by solvent. (C) 1996 Elsevier Science Ltd

引用

收藏

页码：3391 / 3394

页数：4

相关论文

共 24 条

[1] MEASUREMENTS OF THE PRODUCTS OF ATMOSPHERIC PHOTOCHEMICAL-REACTIONS IN LABORATORY STUDIES AND IN AMBIENT AIR-RELATIONSHIPS BETWEEN OZONE AND OTHER PRODUCTS [J].

ALTSHULLER, AP .

ATMOSPHERIC ENVIRONMENT, 1983, 17 (12) :2383-2427

[2] PHOTOIONIZATION MASS-SPECTROMETER STUDIES OF GAS-PHASE OZONE-OLEFIN REACTIONS [J].

ATKINSON, R ;

FINLAYSON, BJ ;

PITTS, JN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (23) :7592-7599

[3] KINETICS AND MECHANISMS OF THE GAS-PHASE REACTIONS OF OZONE WITH ORGANIC-COMPOUNDS UNDER ATMOSPHERIC CONDITIONS [J].

ATKINSON, R ;

CARTER, WPL .

CHEMICAL REVIEWS, 1984, 84 (05) :437-470

[4] OH RADICAL PRODUCTION FROM THE GAS-PHASE REACTIONS OF O-3 WITH A SERIES OF ALKENES UNDER ATMOSPHERIC CONDITIONS [J].

ATKINSON, R ;

ASCHMANN, SM .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1993, 27 (07) :1357-1363

[5]

Bailey P. S., 1978, OZONATION ORGANIC CH, V1

[6]

CASTONGUAY J, 1969, CAN J CHEM, V57, P919

[7] LOW-PRESSURE GAS-PHASE OZONE-OLEFIN REACTIONS - CHEMILUMINESCENCE, KINETICS, AND MECHANISMS [J].

FINLAYSON, BJ ;

PITTS, JN ;

ATKINSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (17) :5356-5367

[8] MICROWAVE AND MASS-SPECTRAL STUDIES OF OZONOLYSIS OF ETHYLENE, PROPYLENE, AND CIS-2-BUTENE AND TRANS-2-BUTENE WITH ADDED OXYGEN-18 FORMALDEHYDE AND ACETALDEHYDE [J].

GILLIES, CW ;

LATTIMER, RP ;

KUCZKOWS.RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (05) :1536-1542

[9] GAS-PHASE REACTION OF OZONE WITH 2-METHYL-2-BUTENE - DICARBONYL FORMATION FROM CRIEGEE BIRADICALS [J].

GROSJEAN, D .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1990, 24 (09) :1428-1432

[10] KINETICS AND ENERGETICS OF THE CRIEGEE INTERMEDIATE IN THE GAS-PHASE .1. THE CRIEGEE INTERMEDIATE IN OZONE ALKENE REACTIONS [J].

HERRON, JT ;

MARTINEZ, RI ;

HUIE, RE .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1982, 14 (03) :201-224