Microstructure and luminescence properties of Co-doped SnO2 nanoparticles synthesized by hydrothermal method

被引:101
作者
Fang, L. M. [1 ]
Zu, X. T. [1 ,2 ]
Li, Z. J. [1 ]
Zhu, S. [3 ,4 ]
Liu, C. M. [1 ]
Wang, L. M. [3 ,4 ]
Gao, F. [5 ]
机构
[1] Univ Elect Sci & Technol China, Dept Appl Phys, Chengdu 610054, Peoples R China
[2] Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
[3] Univ Michigan, Dept Nucl Engn & Radiol Sci, Ann Arbor, MI 48109 USA
[4] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA
[5] Pacific NW Natl Lab, Richland, WA 99352 USA
关键词
D O I
10.1007/s10854-007-9543-7
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Co-doped SnO2 nanoparticles were synthesized by a simple hydrothermal method, and characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Transmission electron microscopy (TEM), UV-Vis diffuse reflectance spectra (DRS) and Photoluminescence spectroscopy (PL). It is found that the SnO2 crystallites with the tetragonal rutile structure formed directly during the hydrothermal process without calcination. The Co-doped SnO2 nanoparticles were spheric and well-dispersed with narrow size distribution. The crystalline size of SnO2 decreased from 5.98 to 2.22 nm when the Co content increased from 0% to 20%. A considerable red shift in the absorbing band edge was observed with increasing of Co dopant.
引用
收藏
页码:868 / 874
页数:7
相关论文
共 29 条
[1]   Grain size effects on H-2 gas sensitivity of thick film resistor using SnO2 nanoparticles [J].
Ansari, SG ;
Boroojerdian, P ;
Sainkar, SR ;
Karekar, RN ;
Aiyer, RC ;
Kulkarni, SK .
THIN SOLID FILMS, 1997, 295 (1-2) :271-276
[2]   THE ROLE OF METAL-ION DOPANTS IN QUANTUM-SIZED TIO2 - CORRELATION BETWEEN PHOTOREACTIVITY AND CHARGE-CARRIER RECOMBINATION DYNAMICS [J].
CHOI, WY ;
TERMIN, A ;
HOFFMANN, MR .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (51) :13669-13679
[3]   Luminescent properties of transparent nanostructured Eu3+ doped SnO2-SiO2 glass-ceramics prepared by the sol-gel method [J].
Del Castillo, J ;
Rodríguez, VD ;
Yanes, AC ;
Méndez-Ramos, J ;
Torres, ME .
NANOTECHNOLOGY, 2005, 16 (05) :S300-S303
[4]   Enhanced photoluminescence of Tb3+ and Eu3+ induced by energy transfer from SnO2 and Si nanocrystallites [J].
Elhouichet, H ;
Othman, L ;
Moadhen, A ;
Ouestlati, M ;
Roger, JA .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2003, 105 (1-3) :8-11
[5]  
FANG LM, IN PRESS J ALLOYS CO
[6]   Dye sensitization of nanocrystalline tin oxide by perylene derivatives [J].
Ferrere, S ;
Zaban, A ;
Gregg, BA .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (23) :4490-4493
[7]   Synthesis and luminescence properties of SnO2 nanoparticles [J].
Gu, F ;
Wang, SF ;
Song, CF ;
Lü, MK ;
Qi, YX ;
Zhou, GJ ;
Xu, D ;
Yuan, DR .
CHEMICAL PHYSICS LETTERS, 2003, 372 (3-4) :451-454
[8]   Luminescent properties of Mn2+-doped SnO2 nanoparticles [J].
Gu, F ;
Wang, SF ;
Lü, MK ;
Qi, YX ;
Zhou, QJ ;
Xu, D ;
Yuan, DR .
INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (07) :882-885
[9]   Photoluminescence properties of SnO2 nanoparticles synthesized by sol-gel method [J].
Gu, F ;
Wang, SF ;
Lü, MK ;
Zhou, GJ ;
Xu, D ;
Yuan, DR .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (24) :8119-8123
[10]   Luminescent characteristics of Eu3+ in SnO2 nanoparticles [J].
Gu, F ;
Wang, SF ;
Lü, MK ;
Qi, YX ;
Zhou, GJ ;
Xu, D ;
Yuan, DR .
OPTICAL MATERIALS, 2004, 25 (01) :59-64