Novel fluorescence sensor for 'small' saccharides

被引：62

作者：

James, TD ^{[1
]}

Shinmori, H ^{[1
]}

Shinkai, S ^{[1
]}

机构：

[1] KYUSHU UNIV, FAC ENGN, DEPT CHEM SCI & TECHNOL, FUKUOKA 812, JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 01期

关键词：

D O I：

10.1039/a606552j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The small binding pocket of compound 2 can exclude 'large' saccharides such as D-glucose, whereas 'small' saccharides such as D-sorbitol are strongly bound as 1:1 complexes; the binding events can be sensitively monitored by changes in the fluorescence intensity.

引用

页码：71 / 72

页数：2

共 13 条

[1]

BISSELL RA, 1993, TOP CURR CHEM, V168, P223

[2]

Czarnik A.W., 1993, INSTRUM SCI TECHNOL, DOI DOI 10.1080/10739149408001201

[3] ALLOSTERIC INTERACTION OF METAL-IONS WITH SACCHARIDES IN A CROWNED DIBORONIC ACID [J].

DENG, G ;

JAMES, TD ;

SHINKAI, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (11) :4567-4572

[4]

James T.D, 1996, ANGEW CHEM, V108, P2038

[5] Fluorescent saccharide receptors: A sweet solution to the design, assembly and evaluation of boronic acid derived PET sensors [J].

James, TD ;

Linnane, P ;

Shinkai, S .

CHEMICAL COMMUNICATIONS, 1996, (03) :281-288

[6] DIBORONIC ACID GLUCOSE CLEFT AND A BISCROWN ETHER METAL SANDWICH ARE ALLOSTERICALLY COUPLED [J].

JAMES, TD ;

SHINKAI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (14) :1483-1485

[7]

JAMES TD, 1994, ANGEW CHEM INT EDIT, V33, P2207, DOI 10.1002/anie.199422071

[8] NOVEL PHOTOINDUCED ELECTRON-TRANSFER SENSOR FOR SACCHARIDES BASED ON THE INTERACTION OF BORONIC ACID AND AMINE [J].

JAMES, TD ;

SANDANAYAKE, KRAS ;

SHINKAI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) :477-478

[9] CHIRAL DISCRIMINATION OF MONOSACCHARIDES USING A FLUORESCENT MOLECULAR SENSOR [J].

JAMES, TD ;

SANDANAYAKE, KRAS ;

SHINKAI, S .

NATURE, 1995, 374 (6520) :345-347

[10] POLYOL COMPLEXES AND STRUCTURE OF THE BENZENEBORONATE ION [J].

LORAND, JP ;

EDWARDS, JO .

JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (06) :769-774

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