Accurate Control of Multishelled ZnO Hollow Microspheres for Dye-Sensitized Solar Cells with High Efficiency

被引:690
作者
Dong, Zhenghong [1 ,3 ]
Lai, Xiaoyong [1 ]
Halpert, Jonathan E. [1 ]
Yang, Nailiang [1 ]
Yi, Luoxin [1 ]
Zhai, Jin [4 ]
Wang, Dan [1 ]
Tang, Zhiyong [2 ]
Jiang, Lei [4 ]
机构
[1] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multi Phase Complex Syst, Beijing 100190, Peoples R China
[2] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
[4] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
multiple shell; hollow spheres; template synthesis; ZnO; dye-sensitized solar cells; CONVERSION EFFICIENCY; SPHERES; NANOCRYSTALLITES; NANOPARTICLES; NANOREACTORS; AGGREGATION; NANOSPHERES; STRATEGY;
D O I
10.1002/adma.201104626
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
A series of multishelled ZnO hollow microspheres with controlled shell number and inter-shell spacing have been successfully prepared by a simple carbonaceous microsphere templating method, whose large surface area and complex multishelled hollow structure enable them load sufficient dyes and multi-reflect the light for enhancing light harvesting and realize a high conversion efficiency of up to 5.6% when used in dye-sensitized solar cells. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1046 / 1049
页数:4
相关论文
共 25 条
[1]
Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J].
Caruso, F ;
Caruso, RA ;
Möhwald, H .
SCIENCE, 1998, 282 (5391) :1111-1114
[2]
Hierarchically structured ZnO film for dye-sensitized solar cells with enhanced energy conversion efficiency [J].
Chou, Tammy P. ;
Zhang, Qifeng ;
Fryxell, Glen E. ;
Cao, Guozhong .
ADVANCED MATERIALS, 2007, 19 (18) :2588-+
[3]
Formation of SnO2 Hollow Nanospheres inside Mesoporous Silica Nanoreactors [J].
Ding, Shujiang ;
Chen, Jun Song ;
Qi, Genggeng ;
Duan, Xiaonan ;
Wang, Zhiyu ;
Giannelis, Emmanuel P. ;
Archer, Lynden A. ;
Lou, Xiong Wen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (01) :21-23
[4]
Sonochemical Preparation of Hierarchical ZnO Hollow Spheres for Efficient Dye-Sensitized Solar Cells [J].
He, Chun-Xiu ;
Lei, Bing-Xin ;
Wang, Yu-Fen ;
Su, Cheng-Yong ;
Fang, Yue-Ping ;
Kuang, Dai-Bin .
CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (29) :8757-8761
[5]
Room-Temperature Formation of Hollow Cu2O Nanoparticles [J].
Hung, Ling-I ;
Tsung, Chia-Kuang ;
Huang, Wenyu ;
Yang, Peidong .
ADVANCED MATERIALS, 2010, 22 (17) :1910-+
[6]
Recent advances in micro-/nano-structured hollow spheres for energy applications: From simple to complex systems [J].
Lai, Xiaoyong ;
Halpert, Jonathan E. ;
Wang, Dan .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (02) :5604-5618
[7]
General Synthesis and Gas-Sensing Properties of Multiple-Shell Metal Oxide Hollow Microspheres [J].
Lai, Xiaoyong ;
Li, Jun ;
Korgel, Brian A. ;
Dong, Zhenghong ;
Li, Zhenmin ;
Su, Fabing ;
Du, Jiang ;
Wang, Dan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (12) :2738-2741
[8]
General Synthesis of Homogeneous Hollow Core-Shell Ferrite Microspheres [J].
Li, Zhenmin ;
Lai, Xiaoyong ;
Wang, Hong ;
Mao, Dan ;
Xing, Chaojian ;
Wang, Dan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (07) :2792-2797
[9]
Monodisperse Yolk-Shell Nanoparticles with a Hierarchical Porous Structure for Delivery Vehicles and Nanoreactors [J].
Liu, Jian ;
Qiao, Shi Zhang ;
Hartono, Sandy Budi ;
Lu, Gao Qing .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (29) :4981-4985
[10]
Thermal oxidation strategy towards porous metal oxide hollow architectures [J].
Liu, Jun ;
Xue, Dongfeng .
ADVANCED MATERIALS, 2008, 20 (13) :2622-+