First lanthanide complexes and unusual coordination behavior of hexakis(3,5-dimethylpyrazolyl)cyclotriphosphazene

被引：31

作者：

Koo, BH

Byun, Y

Hong, E

Kim, Y

Do, Y ^{[1
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea

[2] Korea Adv Inst Sci & Technol, Ctr Mol Sci, Taejon 305701, South Korea

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 11期

关键词：

D O I：

10.1039/a801988f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of hexakis(3,5-dimethylpyrazolyl)cyclotriphosphazene (L) with LnCl(3) (Ln = La, Ce, Nd, Sm) affords new mononuclear lanthanophosphazenes [L.LnCl(3)] with hendecahedral coordination polyhedron in which the ligand L employs an unprecedented kappa(5)N binding core consisting of one cyclotriphosphazene ring nitrogen atom and four pyridinic nitrogen atoms of two sets of geminal pyrazolyl groups.

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收藏

页码：1227 / 1228

页数：2

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