Sidewall epoxidation of single-walled carbon nanotubes: A theoretical prediction

被引：23

作者：

Lu, X ^{[1
]}

Yuan, QH

Zhang, QN

机构：

[1] Xiamen Univ, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China

[2] Xiamen Univ, Ctr Theoret Chem, Dept Chem, Xiamen 361005, Peoples R China

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 19期

关键词：

D O I：

10.1021/ol035407y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] By means of a two-layered ONIOM approach, we predict that sidewall epoxidation of single-walled carbon nanotubes (SWNTs) with dioxiranes is viable. The SWNT epoxides thus produced could be precursors for further chemical modification of SWNTs, given the abundant and well-established chemistry of organic epoxides. This opens the door for routine chemical manipulation of SWNTs.

引用

页码：3527 / 3530

页数：4

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