Preparation of 2-alkylidene oxetanes: An investigation of the Paterno-Buchi reaction between aliphatic aldehydes and allenes

被引：16

作者：

Howell, AR

Fan, R

Truong, A

机构：

[1] Department of Chemistry, University of Connecticut, Storrs

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 48期

关键词：

D O I：

10.1016/S0040-4039(96)02001-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Preliminary results of an examination of factors influencing the stoichiometry and regioselectivity of the Paterno-Buchi reaction between aliphatic aldehydes and nonsymmetrical allenes are divulged. Surprisingly little regioselectivity was seen with 3-methyl-1,2-butadiene (6); however, 1-ethoxy-1,2-propadiene (14) provided a single regioisomer. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：8651 / 8654

页数：4

共 16 条

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