The multiple convolution integral: A new method for modeling multistage continuous leaching reactors

被引:17
作者
Dixon, DG
机构
[1] Dept. of Met. and Mat. Engineering, University of British Columbia, Vancouver, BC V6T 1Z4
关键词
leaching; reactor design; hydrometallurgy; population balance;
D O I
10.1016/0009-2509(96)00334-X
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A new method is presented for modeling multiparticle leaching kinetics in multistage continuous reactors at steady state. The method involves recasting the kinetics of any given leaching reaction into a linear function of time, and then solving a multiple convolution integral over residence time for the mass-weighted probability density of the resulting time-linear variable after passing through N mixed-how reactors in series. The fraction of leachable solids unreacted is then found by integrating this probability density function over all values of the time-linear variable, which is a known function of particle size. The entire model may be solved numerically in a single step using Gaussian quadrature. This new method represents an alternative to both the segregated flow model and the population balance model, combining the simplicity and ease of application of the former with the rigorousness of the latter. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:4759 / 4767
页数:9
相关论文
共 18 条
[1]   CONVERSION AND EXTRACTION EFFICIENCIES FOR GROUND PARTICLES IN HETEROGENEOUS PROCESS REACTORS [J].
BARTLETT, RW .
METALLURGICAL TRANSACTIONS, 1971, 2 (11) :2999-&
[2]  
Carnahan B., 1969, APPL NUMERICAL METHO
[3]   MICRO-MIXING IN CONTINUOUS PARTICULATE REACTORS [J].
CRUNDWELL, FK .
CHEMICAL ENGINEERING SCIENCE, 1994, 49 (23) :3887-3896
[4]   THE MODELING OF PARTICULATE LEACHING REACTORS - THE POPULATION BALANCE APPROACH [J].
CRUNDWELL, FK ;
BRYSON, AW .
HYDROMETALLURGY, 1992, 29 (1-3) :275-295
[5]  
Feller W., 1966, INTRO PROBABILITY TH, VII
[6]  
Herbst J. A., 1979, RATE PROCESSES EXTRA
[7]  
HERBST JA, 1975, AIME ANN M
[8]   SOME PROBLEMS IN PARTICLE TECHNOLOGY - A STATISTICAL MECHANICAL FORMULATION [J].
HULBURT, HM ;
KATZ, S .
CHEMICAL ENGINEERING SCIENCE, 1964, 19 (08) :555-574
[9]  
Levenspiel O., 1972, CHEM REACTION ENG
[10]   MATHEMATICAL-MODELING OF AN EXOTHERMIC LEACHING REACTION SYSTEM - PRESSURE OXIDATION OF WIDE SIZE ARSENOPYRITE PARTICULATES [J].
PAPANGELAKIS, VG ;
BERK, D ;
DEMOPOULOS, GP .
METALLURGICAL TRANSACTIONS B-PROCESS METALLURGY, 1990, 21 (05) :827-837