Ro-vibrational Stark effect on H2 and D2 molecules adsorbed in NaA zeolite

被引：6

作者：

Bras, N ^{[1
]}

机构：

[1] Univ Paris 06, Lab Milieux Desordonnes & Heterogenes, CNRS, UMR C7603, F-75252 Paris 05, France

来源：

JOURNAL OF CHEMICAL PHYSICS | 1999年 / 110卷 / 12期

关键词：

D O I：

10.1063/1.478494

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In order to explain the induced infrared bands of H-2 and D-2 adsorbed in NaA zeolites the Stark effect on the ro-vibrational levels of these molecules is considered for electric fields created by various charge distributions. The shift and intensity of the induced ro-vibration transitions are calculated. (C) 1999 American Institute of Physics. [S0021-9606(99)70411-3].

引用

页码：5943 / 5951

页数：9

共 20 条

[1] DIFFUSE-REFLECTANCE FOURIER-TRANSFORM INFRARED STUDIES OF HYDROGEN ADSORBED ON SODIUM ZEOLITES [J].

BECK, K ;

PFEIFER, H ;

STAUDTE, B .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (21) :3995-3998

[2] THE VIBRATIONAL STARK-EFFECT [J].

BISHOP, DM .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (04) :3179-3184

[3] DIFFUSION OF H2 AND HD IN ZEOLITES - QUANTUM EFFECTS AT 100-K [J].

BOUCHAUD, JP ;

DELARA, EC ;

KAHN, R .

EUROPHYSICS LETTERS, 1992, 17 (07) :583-587

[4] ELECTRIC-FIELD EFFECT OBSERVED ON THE INFRARED-SPECTRA OF THE N2O MOLECULE ADSORBED IN NAA ZEOLITE [J].

BRAS, N ;

DELARA, EC .

JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (18) :6990-6999

[5]

Buckingham A. D., 1967, ADV CHEM PHYS, V12, P107, DOI DOI 10.1002/9780470143582.CH2

[6]

ELHABIB I, 1991, THESIS U PARIS SUD

[7] MOLECULAR-MOTION STUDIES OF A2 MOLECULES ENCAGED IN ZEOLITES [J].

FORSTER, H ;

SCHULDT, M .

JOURNAL OF MOLECULAR STRUCTURE, 1978, 47 (MAY) :339-343

[8] INDUCED IR OVERTONE AND FUNDAMENTAL BANDS OF ISOTOPIC H-2-MOLECULES ADSORBED IN NACAA ZEOLITES [J].

FORSTER, H ;

FREDE, W .

INFRARED PHYSICS, 1984, 24 (2-3) :151-156

[9]

Herzberg G., 1950, MOL SPECTRA MOL STRU

[10]

Huber K. P., 1979, MOL SPECTRA MOL STRU

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