Atmospheric residence time of CH3Br estimated from the Junge spatial variability relation

被引:23
作者
Colman, JJ [1 ]
Blake, DR [1 ]
Rowland, FS [1 ]
机构
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
关键词
D O I
10.1126/science.281.5375.392
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The atmospheric residence time for methyl bromide (CH,Br) has been estimated as 0.8 +/- 0.1 years from its empirical spatial variability relative to C2H6. C2Cl4, CHCl3, and CH3Cl. This evaluation of the atmospheric residence time, based on Junge's 1963 general proposal, provides an estimate for CH3Br that is independent of source and sink estimates. Methyl bromide from combined natural and anthropogenic sources furnishes about half of the bromine that enters the stratosphere, where it plays an important role in ozone destruction. This residence time is consistent with the 0.7-year value recently calculated for CH3Br from the combined strength estimates for its known significant sinks.
引用
收藏
页码:392 / 396
页数:5
相关论文
共 16 条
[1]  
[Anonymous], 1963, AIR CHEM RADIOACTIVI, DOI DOI 10.1002/QJ.49709038422
[2]  
BAKER MB, 1979, TELLUS, V31, P39, DOI 10.1111/j.2153-3490.1979.tb00880.x
[3]  
CICERONE RJ, 1997, 1997 METH BROM STAT
[4]  
DeMore W.B., 1997, CHEM KINETICS PHOTOC
[5]   NUCLEOPHILIC-SUBSTITUTION RATES AND SOLUBILITIES FOR METHYL HALIDES IN SEAWATER [J].
ELLIOTT, S ;
ROWLAND, FS .
GEOPHYSICAL RESEARCH LETTERS, 1993, 20 (11) :1043-1046
[6]   FLUCTUATIONS IN TRACE GAS CONCENTRATIONS IN TROPOSPHERE [J].
GIBBS, AG ;
SLINN, WGN .
JOURNAL OF GEOPHYSICAL RESEARCH, 1973, 78 (03) :574-576
[7]  
HAMRUD M, 1983, TELLUS, V358, P295
[8]  
JAESCHKE R, 1982, CHEM UNPOLLUTED POLL, P341
[9]   RESIDENCE TIME AND VARIABILITY OF TROPOSPHERIC TRACE GASES [J].
JUNGE, CE .
TELLUS, 1974, 26 (04) :477-488
[10]   Removal of methyl bromide in coastal seawater: Chemical and biological rates [J].
King, DB ;
Saltzman, ES .
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS, 1997, 102 (C8) :18715-18721