Size effect on the electron-spin resonance of Pr0.7Sr0.3-xCaxMnO3

被引:23
作者
Gundakaram, R [1 ]
Lin, JG [1 ]
Huang, CY [1 ]
机构
[1] Natl Taiwan Univ, Ctr Condensed Matter Sci, Taipei 10764, Taiwan
关键词
D O I
10.1103/PhysRevB.58.12247
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electron-spin-resonance (ESR) measurements have been performed on samples of the system Pr-0.7(Sr0.3 - xCax)MnO3. Substitution of Ca in the Sr site changes the effective ionic radius of the A site, but the average Mn valence remains unchanged. The variation of the resonance linewidth, magnetization, and activation energy as functions of temperature and Ca concentration has been studied. The linewidth increases with an increase in the Ca content, which has been explained on the basis of the change in the tolerance factor. For x<0.1, the ESR line intensity varies exponentially with temperature with an activation energy dependent on x. However, for samples with 0.1 less than or equal to x less than or equal to 0.3, there is a change in the activation energy in the temperature range of the present study (110-550 K). [S0163-1829(98)05842-1].
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页码:12247 / 12251
页数:5
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