Electropolymerization of high stable poly(3,4-ethylenedioxythiophene) in ionic liquids and its potential applications in electrochemical capacitor

被引：140

作者：

Liu, Keke ^{[1
]}

Hu, Zhenglong ^{[1
]}

Xue, Rong ^{[1
]}

Zhang, Jianrong ^{[1
]}

Zhu, Junjie ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Analyt Chem Life Sci, Nanjing 210093, Peoples R China

来源：

JOURNAL OF POWER SOURCES | 2008年 / 179卷 / 02期

基金：

中国国家自然科学基金;

关键词：

supercapacitor; ionic liquids; capacitance; electropolymerization; conducting polymers; poly(3,4-ethylenedioxythiophene);

D O I：

10.1016/j.jpowsour.2008.01.024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Poly(3,4-ethylenedioxythiophene) (PEDOT) has been successfully electropolymerized using a purified 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) as both the growth medium and the supporting electrolyte. The electrochemical performance of the PEDOT thin film was investigated in I mol L-1 H2SO4 solution. It possesses nearly ideal capacitive property, and its specific capacitance is about 130Fg(-1). Compared with other conducting polymers, enhanced cycling lifetime (up to 70,000 cycles), which is close to that of active carbon materials, was observed on repetitive redox cycling. (c) 2008 Elsevier B.V. All rights reserved.

引用

收藏

页码：858 / 862

页数：5

相关论文

共 54 条

[1] Ionic liquids for hybrid supercapacitors [J].

Balducci, A ;

Bardi, U ;

Caporali, S ;

Mastragostino, M ;

Soavi, F .

ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (06) :566-570

[2] Electrochemical properties of alkali metals in 1-butyl-3-methylimidazolium hexafluorophosphate [J].

Boxall, DL ;

Osteryoung, RA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (06) :E185-E188

[3] Biomimetic synthesis of water-soluble conducting copolymers/homopolymers of pyrrole and 3,4-ethylenedioxythiophene [J].

Bruno, FF ;

Fossey, SA ;

Nagarajan, S ;

Nagarajan, R ;

Kumar, J ;

Samuelson, LA .

BIOMACROMOLECULES, 2006, 7 (02) :586-589

[4] Fast and reversible surface redox reaction in nanocrystalline vanadium nitride supercapacitors [J].

Choi, Daiwon ;

Blomgren, George E. ;

Kumta, Prashant N. .

ADVANCED MATERIALS, 2006, 18 (09) :1178-+

[5]

Conway B. E., 1999, ELECTROCHEMICAL SUPE

[6] Electrochemical synthesis and in situ spectroelectrochemical characterization of poly(3,4-ethylenedioxythiophene) (PEDOT) in room temperature ionic liouids [J].

Damlin, P ;

Kvarnström, C ;

Ivaska, A .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2004, 570 (01) :113-122

[7] Performance evaluation of poly 3-(phenylthiophene) derivatives as active materials for electrochemical capacitor applications [J].

Ferraris, JP ;

Eissa, MM ;

Brotherston, ID ;

Loveday, DC .

CHEMISTRY OF MATERIALS, 1998, 10 (11) :3528-3535

[8] Preparation and electrochemical evaluation of poly (3-phenylthiophene) derivatives: potential materials for electrochemical capacitors [J].

Ferraris, JP ;

Eissa, MM ;

Brotherston, ID ;

Loveday, DC ;

Moxey, AA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 459 (01) :57-69

[9] Influence of pore structure on electric double-layer capacitance of template mesoporous carbons [J].

Fuertes, AB ;

Pico, F ;

Rojo, JM .

JOURNAL OF POWER SOURCES, 2004, 133 (02) :329-336

[10] STRUCTURE OF 1-ETHYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE - MODEL FOR ROOM-TEMPERATURE MOLTEN-SALTS [J].

FULLER, J ;

CARLIN, RT ;

DELONG, HC ;

HAWORTH, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (03) :299-300

← 1 2 3 4 5 6 →