Inorganic heterogeneous catalysts for biodiesel production from vegetable oils

被引:290
作者
Endalew, Abebe K. [1 ]
Kiros, Yohannes [1 ]
Zanzi, Rolando [1 ]
机构
[1] KTH Royal Inst Technol, Dept Chem Engn & Technol, S-10044 Stockholm, Sweden
关键词
Biodiesel; Edible and non-edible oils; Inorganic heterogeneous catalysts; Free fatty acids; Transesterification; FREE FATTY-ACID; EARTH METAL-OXIDES; FRIEDEL-CRAFTS ACYLATION; SOLID BASE CATALYSTS; MG-AL HYDROTALCITE; WASTE COOKING OIL; SOYBEAN OIL; FUEL PRODUCTION; SUNFLOWER OIL; HETEROPOLYACID CATALYSTS;
D O I
10.1016/j.biombioe.2011.06.011
中图分类号
S2 [农业工程];
学科分类号
082806 [农业信息与电气工程];
摘要
Biofuels are renewable solutions to replace the ever dwindling energy reserves and environmentally pollutant fossil liquid fuels when they are produced from low cost sustainable feedstocks. Biodiesel is mainly produced from vegetable oils or animal fats by the method of transesterification reaction using catalysts. Homogeneous catalysts are conventionally used for biodiesel production. Unfortunately, homogeneous catalysts are associated with problems which might increase the cost of production due to separation steps and emission of waste water. Inorganic heterogeneous catalysts are potentially low cost and can solve many of the problems encountered in homogeneous catalysts. Many solid acid and base inorganic catalysts have been studied for the transesterification of various vegetables oils. The work of many researchers on the development of active, tolerant to water and free fatty acids (FFA), as well as stable inorganic catalysts for biodiesel production from vegetable oils are reviewed and discussed. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3787 / 3809
页数:23
相关论文
共 173 条
[1]
Jatropha biodiesel fueling sustainability? [J].
Achten, Wouter M. J. ;
Mathijs, Erik ;
Verchot, Louis ;
Singh, Virendra P. ;
Aerts, Raf ;
Muys, Bart .
BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR, 2007, 1 (04) :283-291
[2]
Alum as a heterogeneous catalyst for the transesterification of palm oil [J].
Aderemi, Benjamin O. ;
Hameed, B. H. .
APPLIED CATALYSIS A-GENERAL, 2009, 370 (1-2) :54-58
[3]
Akbar E., 2009, European Journal of Scientific Research, P396
[4]
Heterogeneous transesterification processes by using CaO supported on zinc oxide as basic catalysts [J].
Alba-Rubio, Ana C. ;
Santamaria-Gonzalez, Jose ;
Merida-Robles, Josefa M. ;
Moreno-Tost, Ramon ;
Martin-Alonso, David ;
Jimenez-Lopez, Antonio ;
Maireles-Torres, Pedro .
CATALYSIS TODAY, 2010, 149 (3-4) :281-287
[5]
CaO supported on mesoporous silicas as basic catalysts for transesterification reactions [J].
Albuquerque, Monica C. G. ;
Jimenez-Urbistondo, Inmaculada ;
Santamaria-Gonzalez, Jose ;
Merida-Robles, Josefa M. ;
Moreno-Tost, Ramon ;
Rodriguez-Castellon, Enrique ;
Jimenez-Lopez, Antonio ;
Azevedo, Diana C. S. ;
Cavalcante, Celio L., Jr. ;
Maireles-Torres, Pedro .
APPLIED CATALYSIS A-GENERAL, 2008, 334 (1-2) :35-43
[6]
Transesterification of ethyl butyrate with methanol using MgO/CaO catalysts [J].
Albuquerque, Monica C. G. ;
Azevedo, Diana C. S. ;
Cavalcante, Celio L., Jr. ;
Santamaria-Gonzalez, Jose ;
Merida-Robles, Josefa M. ;
Moreno-Tost, Ramon ;
Rodriguez-Castellon, Enrique ;
Jimenez-Lopez, Antonio ;
Maireles-Torres, Pedro .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 300 (1-2) :19-24
[7]
Synthesis of biodiesel with heterogeneous NaOH/alumina catalysts:: Comparison with homogeneous NaOH [J].
Arzamendi, G. ;
Campo, I. ;
Arguinarena, E. ;
Sanchez, M. ;
Montes, M. ;
Gandia, L. M. .
CHEMICAL ENGINEERING JOURNAL, 2007, 134 (1-3) :123-130
[8]
Synthesis of biodiesel from sunflower oil with silica-supported NaOH catalysts [J].
Arzamendi, Gurutze ;
Campo, Idoia ;
Arguinarena, Eider ;
Sanchez, Maialen ;
Montes, Mario ;
Gandia, Luis M. .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2008, 83 (06) :862-870
[9]
*AX, PROC CAT ADS ADV SER
[10]
Room-temperature transesterification of edible and nonedible oils using a heterogeneous strong basic Mg/La catalyst [J].
Babu, N. Seshu ;
Sree, Rekha ;
Prasad, P. S. Sai ;
Lingaiah, N. .
ENERGY & FUELS, 2008, 22 (03) :1965-1971