4α-methyl-5α,14β-ergosta-8,24(241)-dien-3β-ol ("triticusterol"):: the first naturally occurring 14β(H)-steroid

被引:4
作者
Akihisa, T
Kokke, WCMC
Koike, K
Kimura, Y
Mizukami, C
Sadaie, A
Maruyama, T
Nikaido, T
机构
[1] Nihon Univ, Coll Sci & Technol, Chiyoda Ku, Tokyo 1018308, Japan
[2] Cauldron Proc Chem, Malvern, PA 19355 USA
[3] Toho Univ, Sch Pharmaceut Sci, Funabashi, Chiba 2748510, Japan
[4] Nihon Univ, Coll Pharm, Funabashi, Chiba 2748555, Japan
[5] Japan Inst Oils & Fats, Other Foods Inspect, Chuo Ku, Tokyo 1030007, Japan
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1999年 / 04期
关键词
D O I
10.1039/a808508k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The structure of triticusterol isolated from the germ oil of wheat (Triticum aestivum L.; Gramineae) was established to be 4 alpha-methyl-5 alpha,14 beta-ergosta-8,24(24(1))-dien-3 beta-ol on the basis of spectroscopic data. This is the first example of a naturally occurring compound with a 14 beta(H)-steroid skeleton.
引用
收藏
页码:497 / 500
页数:4
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