The preparation of fatty acid esters by means of catalytic reactions

被引:70
作者
Bondioli, P [1 ]
机构
[1] Stn Sperimentale Oli & Grassi, I-20133 Milan, Italy
关键词
biodiesel; biofuel; biolubricant; catalyst; esterification; renewable material; transesterification;
D O I
10.1023/B:TOCA.0000013542.58801.49
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A review of actually available techniques for the preparation of esters derived form natural oils and fats is presented. A wide choice of catalysts, either homogeneous or heterogeneous, is currently available. This paper evaluates in detail the possibilities for the preparation of fatty acid esters with different alcohols and discusses the criteria for a correct choice. The different problems related to the preparation of esters with low molecular weight monoalcohols and of polyolesters with polyalcohols are discussed. The last part of the paper is devoted to the evaluation of ion-exchange resins as effective catalysts for the preparation of fatty acid esters with low molecular weight monoalcohols.
引用
收藏
页码:77 / 82
页数:6
相关论文
共 22 条
[1]  
ASDIH M, 1990, REV FR CORPS GRAS, V37, P241
[2]   Synthesis of biolubricants with high viscosity and high oxidation stability [J].
Bondioli, P ;
Della Bella, L ;
Manglaviti, A .
OCL-OLEAGINEUX CORPS GRAS LIPIDES, 2003, 10 (02) :150-154
[3]  
BONDIOLI P, 1997, RIV IT SOSTANZE GRAS, V74, P137
[4]  
BONDIOLI P, 2001, CHEM TECHNOL OILS, P74
[5]  
CHOO YM, 1990, P WORLD C OL 21 CENT, P292
[6]   VARIABLES AFFECTING THE YIELDS OF FATTY ESTERS FROM TRANSESTERIFIED VEGETABLE-OILS [J].
FREEDMAN, B ;
PRYDE, EH ;
MOUNTS, TL .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1984, 61 (10) :1638-1643
[7]   METHANOLYSIS OF TRIGLYCERIDES [J].
HARTMAN, L .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1956, 33 (03) :129-129
[8]  
LEGRAND J, 1998, P EUR C CROPS GREEN
[9]  
MARCHAL P, 1985, REV FR CORPS GRAS, V32, P429
[10]  
*MITS CHEM CORP, 1995, DIAION MAN ION EXCH, V2, P184