Electrochemically Reduced Single-Layer MoS2 Nanosheets: Characterization, Properties, and Sensing Applications

被引：376

作者：

Wu, Shixin ^{[1
]}

Zeng, Zhiyuan ^{[1
]}

He, Qiyuan ^{[1
]}

Wang, Zhijuan ^{[1
]}

Wang, Shi Jie ^{[2
]}

Du, Yaping ^{[1
]}

Yin, Zongyou ^{[1
]}

Sun, Xuping ^{[3
]}

Chen, Wei ^{[4
,5
]}

Zhang, Hua ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[2] Inst Mat Res & Engn, Singapore 117602, Singapore

[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China

[4] Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore

[5] Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore

来源：

SMALL | 2012年 / 8卷 / 14期

基金：

新加坡国家研究基金会;

关键词：

MoS2; nanosheets; electrochemical reduction; sensors; glucose; dopamine; GLUCOSE-OXIDASE; GRAPHENE OXIDE; EXFOLIATION; CARBON; WS2; INTERCALATION; PERFORMANCES; TRANSISTORS; NANOTUBES; DOPAMINE;

D O I：

10.1002/smll.201200044

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical study of single-layer, 2D MoS2 nanosheets reveals a reduction peak in the cyclic voltammetry in NaCl aqueous solution. The electrochemically reduced MoS2 (rMoS2) shows good conductivity and fast electron transfer rate in the [Fe(CN)6]3-/4- and [Ru(NH3)6]2+/3+ redox systems. The obtained rMoS2 can be used for glucose detection. In addition, it can selectively detect dopamine in the presence of ascorbic acid and uric acid. This novel material, rMoS2, is believed to be a good electrode material for electrochemical sensing applications.

引用

页码：2264 / 2270

页数：7

共 41 条

[1] Single-layer MoS2/graphene dispersed in amorphous carbon: towards high electrochemical performances in rechargeable lithium ion batteries [J].

Chang, Kun ;

Chen, Weixiang .

JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (43) :17175-17184

[2] Graphene-like MoS2/amorphous carbon composites with high capacity and excellent stability as anode materials for lithium ion batteries [J].

Chang, Kun ;

Chen, Weixiang ;

Ma, Lin ;

Li, Hui ;

Li, He ;

Huang, Feihe ;

Xu, Zhude ;

Zhang, Qingbo ;

Lee, Jim-Yang .

JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (17) :6251-6257

[3] Graphene-based materials in electrochemistry [J].

Chen, Da ;

Tang, Longhua ;

Li, Jinghong .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (08) :3157-3180

[4] Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials [J].

Coleman, Jonathan N. ;

Lotya, Mustafa ;

O'Neill, Arlene ;

Bergin, Shane D. ;

King, Paul J. ;

Khan, Umar ;

Young, Karen ;

Gaucher, Alexandre ;

De, Sukanta ;

Smith, Ronan J. ;

Shvets, Igor V. ;

Arora, Sunil K. ;

Stanton, George ;

Kim, Hye-Young ;

Lee, Kangho ;

Kim, Gyu Tae ;

Duesberg, Georg S. ;

Hallam, Toby ;

Boland, John J. ;

Wang, Jing Jing ;

Donegan, John F. ;

Grunlan, Jaime C. ;

Moriarty, Gregory ;

Shmeliov, Aleksey ;

Nicholls, Rebecca J. ;

Perkins, James M. ;

Grieveson, Eleanor M. ;

Theuwissen, Koenraad ;

McComb, David W. ;

Nellist, Peter D. ;

Nicolosi, Valeria .

SCIENCE, 2011, 331 (6017) :568-571

[5] SINGLE CRYSTALS OF MOS2 SEVERAL MOLECULAR LAYERS THICK [J].

FRINDT, RF .

JOURNAL OF APPLIED PHYSICS, 1966, 37 (04) :1928-&

[6] Structures of exfoliated single layers of WS2, MoS2, and MoSe2 in aqueous suspension -: art. no. 125407 [J].

Gordon, RA ;

Yang, D ;

Crozier, ED ;

Jiang, DT ;

Frindt, RF .

PHYSICAL REVIEW B, 2002, 65 (12) :1254071-1254079

[7] Transparent, Flexible, All-Reduced Graphene Oxide Thin Film Transistors [J].

He, Qiyuan ;

Wu, Shixin ;

Gao, Shuang ;

Cao, Xiehong ;

Yin, Zongyou ;

Li, Hai ;

Chen, Peng ;

Zhang, Hua .

ACS NANO, 2011, 5 (06) :5038-5044

[8] Exfoliated and restacked MoS2 and WS2:: Ionic or neutral species?: Encapsulation and ordering of hard electropositive cations [J].

Heising, J ;

Kanatzidis, MG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (50) :11720-11732

[9] Graphene-based composites [J].

Huang, Xiao ;

Qi, Xiaoying ;

Boey, Freddy ;

Zhang, Hua .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (02) :666-686

[10] Graphene-Based Materials: Synthesis, Characterization, Properties, and Applications [J].

Huang, Xiao ;

Yin, Zongyou ;

Wu, Shixin ;

Qi, Xiaoying ;

He, Qiyuan ;

Zhang, Qichun ;

Yan, Qingyu ;

Boey, Freddy ;

Zhang, Hua .

SMALL, 2011, 7 (14) :1876-1902

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