Chiral Nematic Mesoporous Carbon Derived From Nanocrystalline Cellulose

被引：192

作者：

Shopsowitz, Kevin E. ^{[1
]}

Hamad, Wadood Y. ^{[2
]}

MacLachlan, Mark J. ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

[2] FPInnovations, Vancouver, BC V6S 2L9, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 46期

基金：

加拿大自然科学与工程研究理事会;

关键词：

carbon; cellulose; liquid crystals; mesoporous materials; self-assembly; MOLECULAR-SIEVES; FILMS; CAPACITORS; BATTERIES; FAMILY;

D O I：

10.1002/anie.201105479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Twisted organization: Pyrolysis of nanocrystalline cellulose (NCC)/silica composite films leads to mesoporous carbon materials with long-range chiral organization (see picture). The NCC acts as a template and the resulting mesoporous carbon has a high specific surface area (>1400 m 2 g -1) and accurately replicates the left-handed helical structure of the chiral nematic NCC films. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10991 / 10995

页数：5

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