Synthesis and characterization of conducting interpenetrating polymer networks for new actuators

被引:75
作者
Plesse, C [1 ]
Vidal, F [1 ]
Randriamahazaka, H [1 ]
Teyssié, D [1 ]
Chevrot, C [1 ]
机构
[1] Univ Cergy Pontoise, LPPI, F-95031 Cergy Pontoise, France
关键词
interpenetrating polymer networks; actuators; synthesis;
D O I
10.1016/j.polymer.2005.03.103
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis of conducting interpenetrating polymer networks (IPNs) for actuator applications is described. The IPNs are synthesized from poly(ethylene oxide) and polybutadiene networks in which the conducting polymer (poly(3,4-ethylenedioxythiophene)), PEDOT, is gradually dispersed, i.e. its content decreases from the outside towards the centre of the film. The conducting IPN morphology was investigated by electrical resistance measurements and DMA. For actuation experiments, aqueous or organic electrolyte solutions were used but the best results were obtained with a room temperature ionic liquid, 1-ethyl-3-methylimidazolium bis-(trifluoromethylsulfonyl)imide (EMITFSI). (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7771 / 7778
页数:8
相关论文
共 24 条
[1]  
[Anonymous], INTERPENETRATING POL
[2]   Conducting polymer artificial muscles [J].
Baughman, RH .
SYNTHETIC METALS, 1996, 78 (03) :339-353
[3]   Hydrophobic, highly conductive ambient-temperature molten salts [J].
Bonhote, P ;
Dias, AP ;
Papageorgiou, N ;
Kalyanasundaram, K ;
Gratzel, M .
INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178
[4]   Electrochemically induced volume changes in poly(3,4-ethylenedioxythiophene) [J].
Chen, XW ;
Xing, KZ ;
Inganas, O .
CHEMISTRY OF MATERIALS, 1996, 8 (10) :2439-2443
[5]  
DEPAOLI MA, 1997, HDB ORGANIC CONDUCTI, V2, P773
[6]   Use of ionic liquids as electrolytes in electromechanical actuator systems based on inherently conducting polymers [J].
Ding, J ;
Zhou, DZ ;
Spinks, G ;
Wallace, G ;
Forsyth, S ;
Forsyth, M ;
MacFarlane, DR .
CHEMISTRY OF MATERIALS, 2003, 15 (12) :2392-2398
[7]   Conducting semi-IPN based on polyaniline and crosslinked poly(vinyl alcohol) [J].
Gangopadhyay, R ;
De, A .
SYNTHETIC METALS, 2002, 132 (01) :21-28
[8]  
Groenendaal BL, 2000, ADV MATER, V12, P481, DOI 10.1002/(SICI)1521-4095(200004)12:7<481::AID-ADMA481>3.0.CO
[9]  
2-C
[10]   Studies on polyaniline filled PU/PMA interpenetrating polymer networks [J].
Jeevananda, T ;
Begum, B ;
Siddaramaiah .
EUROPEAN POLYMER JOURNAL, 2001, 37 (06) :1213-1218