Thermal Generation of Pentacenes from Soluble 6,13-Dihydro-6,13-ethenopentacene Precursors by a Diels-Alder-retro-Diels-Alder Sequence with 3,6-Disubstituted Tetrazines

被引：16

作者：

Bula, Rafael P. ^{[1
]}

Oppel, Iris M. ^{[2
]}

Bettinger, Holger F. ^{[1
]}

机构：

[1] Univ Tubingen, Inst Organ Chem, D-72076 Tubingen, Germany

[2] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 07期

关键词：

PHOTOCHEMICAL-SYNTHESIS; THIN-FILMS; FUNCTIONALIZED ACENES; DERIVATIVES; GROWTH;

D O I：

10.1021/jo202450u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3,6-Substituted tetrazines 2 (a: R-2 = 2-pyridyl or b: CO2Me) react with 2,3,9,10-(R-1)(4)-dihydro-6,13-ethenopentacene 3 in solution at elevated temperature to the corresponding pentacene 1 (a: R-1 = H, b: OBn, c: F).

引用

页码：3538 / 3542

页数：5

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