Theoretical values of the dipole polarizabilities of H2+(0,0) and D2+(0,0)

被引：18

作者：

Moss, RE ^{[1
]}

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

PHYSICAL REVIEW A | 1998年 / 58卷 / 06期

关键词：

D O I：

10.1103/PhysRevA.58.4447

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Calculated values of the dipole polarizabilities of the ground states of H-2(+) and D-2(+) are in good agreement with the experimental values of Jacobson er al. [Phys. Rev. A 56, R4361 (1997); 57, 4065(E) (1998)]. Two different approaches are used involving a variational method and a scattering method, the latter providing the prospect of calculating accurate nonadiabatic molecular properties for many of the vibration-rotation levels of the hydrogen molecular cation. [S1050-2947(98)02512-8].

引用

页码：4447 / 4448

页数：2

共 11 条

[1] CALCULATIONS OF VIBRATION-ROTATION ENERGY-LEVELS OF HD+ [J].

BALINTKURTI, GG ;

MOSS, RE ;

SADLER, IA ;

SHAPIRO, M .

PHYSICAL REVIEW A, 1990, 41 (09) :4913-4921

[2] MOMENT FUNCTIONS (INCLUDING STATIC DIPOLE POLARIZABILITIES) AND RADIATIVE-CORRECTIONS FOR H2+ [J].

BISHOP, DM ;

CHEUNG, LM .

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1978, 11 (18) :3133-3144

[3] BREAKDOWN OF THE BORN-OPPENHEIMER APPROXIMATION IN THE CALCULATION OF ELECTRIC HYPERPOLARIZABILITIES [J].

BISHOP, DM ;

SOLUNAC, SA .

PHYSICAL REVIEW LETTERS, 1985, 55 (19) :1986-1988

[4] AN ANALYSIS OF THE INTERACTION BETWEEN A DISTANT POINT-CHARGE AND H-2(+) [J].

BISHOP, DM ;

LAM, B .

MOLECULAR PHYSICS, 1988, 65 (03) :679-688

[5] Determination of the dipole polarizabilities of H2+(0,0) and D2+(0,0) by microwave spectroscopy of high-L Rydberg states of H2 and D2 (vol 56, pg R4361, 1997) [J].

Jacobson, PL ;

Fisher, DS ;

Fehrenbach, CW ;

Sturrus, WG ;

Lundeen, SR .

PHYSICAL REVIEW A, 1998, 57 (05) :4065-4065

[6] Determination of the dipole polarizabilities of H-2(+)(0,0) and D-2(+)(0,0) by microwave spectroscopy of high-L Rydberg states of H-2 and D-2 [J].

Jacobson, PL ;

Fisher, DS ;

Fehrenbach, CW ;

Sturrus, WG ;

Lundeen, SR .

PHYSICAL REVIEW A, 1997, 56 (06) :R4361-R4364

[7] THE 2P-SIGMA(U)-1S-SIGMA(G) ELECTRONIC-SPECTRUM OF D-2(+) [J].

MOSS, RE .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (21) :3851-3855

[8] CALCULATIONS FOR VIBRATION-ROTATION LEVELS OF HD+, IN PARTICULAR FOR HIGH N [J].

MOSS, RE .

MOLECULAR PHYSICS, 1993, 78 (02) :371-405

[9] VARIATIONAL CALCULATIONS FOR HIGH J, LOW NU-LEVELS OF HD+ [J].

MOSS, RE ;

SADLER, IA .

MOLECULAR PHYSICS, 1989, 68 (05) :1015-1031

[10]

SHERTZER J, COMMUNICATION

← 1 2 →