Pd nanoparticles for C-C coupling reactions

被引：772

作者：

Balanta, Angelica ^{[1
]}

Godard, Cyril ^{[1
]}

Claver, Carmen ^{[1
]}

机构：

[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43007, Spain

来源：

CHEMICAL SOCIETY REVIEWS | 2011年 / 40卷 / 10期

关键词：

POLYMER-INCARCERATED PALLADIUM; HETEROGENEOUS CATALYTIC-SYSTEM; NOBLE-METAL NANOPARTICLES; BLOCK-COPOLYMER MICELLES; SUZUKI-MIYAURA REACTION; HECK REACTIONS; IONIC LIQUID; IN-SITU; NANOSIZED PALLADIUM; ACTIVE CATALYST;

D O I：

10.1039/c1cs15195a

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The catalytic formation of C-C bonds is one of the most useful transformations in organic synthesis. Over the last decade, the use of transition metal nanoparticles (NPs) in catalysis has attracted much interest and their use in C-C bond formation reactions constitutes one of their most important applications, including the Suzuki, Heck, and Sonogashira reactions. This tutorial review highlights recent work in this active area, considering the stabilising agents used to prepare the NPs, the catalytic results and the recycling possibilities.

引用

页码：4973 / 4985

页数：13

共 134 条

[1]

HIGH-DISPERSION DIRECT-CURRENT SPUTTERED PLATINUM-TIO2 POWDER CATALYST ACTIVE IN ETHANE HYDROGENOLYSIS [J].

ALBERS, P ;

SEIBOLD, K ;

MCEVOY, AJ ;

KIWI, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (04) :1510-1515

[2]

Preparation of nanoparticulate metal catalysts in porous supports using an ionic liquid route;: hydrogenation and C-C coupling [J].

Anderson, K ;

Fernández, SC ;

Hardacre, C ;

Marr, PC .

INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (01) :73-76

[3]

Nanoparticles as recyclable catalysts: The frontier between homogeneous and heterogeneous catalysis [J].

Astruc, D ;

Lu, F ;

Aranzaes, JR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (48) :7852-7872

[4]

Palladium nanoparticles as efficient green homogeneous and heterogeneous carbon-carbon coupling precatalysts: A unifying view [J].

Astruc, Didier .

INORGANIC CHEMISTRY, 2007, 46 (06) :1884-1894

[5]

Palladium colloid stabilized by block copolymer micelles as an efficient catalyst for reactions of C-C and C-heteroatom bond formation [J].

Beletskaya, IP ;

Kashin, AN ;

Litvinov, AE ;

Tyurin, VS ;

Valetsky, PM ;

van Koten, G .

ORGANOMETALLICS, 2006, 25 (01) :154-158

[6]

First palladium-catalyzed Heck reactions with efficient colloidal catalyst systems [J].

Beller, M ;

Fischer, H ;

Kuhlein, K ;

Reisinger, CP ;

Herrmann, WA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 520 (1-2) :257-259

[7]

Perfluoro-tagged, phosphine-free palladium nanoparticles supported on silica gel: application to alkynylation of aryl halides, Suzuki-Miyaura cross-coupling, and Heck reactions under aerobic conditions [J].

Bernini, Roberta ;

Cacchi, Sandro ;

Fabrizi, Giancarlo ;

Forte, Giovanni ;

Petrucci, Francesco ;

Prastaro, Alessandro ;

Niembro, Sandra ;

Shafir, Alexandr ;

Vallribera, Adelina .

GREEN CHEMISTRY, 2010, 12 (01) :150-158

[8]

Microgel-stabilized metal nanoclusters: Improved solid-state stability and catalytic activity in Suzuki couplings [J].

Biffis, A ;

Sperotto, E .

LANGMUIR, 2003, 19 (22) :9548-9550

[9]

Functionalised microgels: novel stabilisers for catalytically active metal colloids [J].

Biffis, A .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 165 (1-2) :303-307

[10]

Nanoscale colloidal metals and alloys stabilized by solvents and surfactants - Preparation and use as catalyst precursors [J].

Bonnemann, H ;

Braun, G ;

Brijoux, W ;

Brinkmann, R ;

Tilling, AS ;

Seevogel, K ;

Siepen, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 520 (1-2) :143-162

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