The evaluation method of smoothing algorithms in voltammetry

被引：8

作者：

Jakubowska, M ^{[1
]}

Piech, R ^{[1
]}

Dzierwa, T ^{[1
]}

Wcislo, J ^{[1
]}

Kubiak, WW ^{[1
]}

机构：

[1] AGH Univ Sci & Technol, Fac Mat Sci & Ceram, PL-30059 Krakow, Poland

来源：

ELECTROANALYSIS | 2003年 / 15卷 / 22期

关键词：

smoothing; voltammetry; calibration curve;

D O I：

10.1002/elan.200302751

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The criterion for testing the influence of smoothing algorithms for the relevant parameters considered in analytical experiment is presented. The proposed approach assumes that the improvement of the whole set of measured curves should be considered. The calibration curve parameters with confidence intervals, correlation coefficient, detection limit, signal to noise ratio and parameters of recovery function are utilized for the evaluation. Performance of evaluation method is presented for several kinds of experimental noises.

引用

页码：1729 / 1736

页数：8

共 23 条

[1] SMOOTHING AND DIFFERENTIATION BY AN ADAPTIVE-DEGREE POLYNOMIAL FILTER [J].