Biotransformation of (-)-maalioxide by Aspergillus niger and Aspergillus cellulosae

被引：8

作者：

Hashimoto, T ^{[1
]}

Noma, Y

Gotoh, Y

Tanaka, M

Takaoka, S

Asakawa, Y

机构：

[1] Tokushima Bunri Univ, Fac Pharmaceut Sci, Tokushima 7708514, Japan

[2] Tokushima Bunri Univ, Fac Human Life Sci, Tokushima 7708514, Japan

来源：

HETEROCYCLES | 2004年 / 62卷

关键词：

Plagiochila sciophila; maalioxide; biotransformation; Aspergillus niger; Aspergillus cellulosae;

D O I：

10.3987/COM-03-S(P)59

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A sesquiterpene cyclic ether, (-)-maalioxide (1) from the liverwort Plagiochila sciophila was biotransformed by Aspergillus niger and A. cellulosae to afford the structurally interesting compounds. The stereostructures of the metabolites were established by a combination of high resolution NMR spectrum, X-Ray crystallographic analysis and the chemical reaction.

引用

页码：655 / 666

页数：12

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