The first example of catalytic N-oxidation of tertiary amines by tungstate-exchanged Mg-Al layered double hydroxide in water:: a green protocol

被引：45

作者：

Choudary, BM ^{[1
]}

Bharathi, B ^{[1
]}

Reddy, CV ^{[1
]}

Kantam, ML ^{[1
]}

Raghavan, KV ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 18期

关键词：

D O I：

10.1039/b104754j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A green process, using a recyclable tungstate-exchanged Mg-Al layered double hydroxide (LDH-WO42-) heterogenised catalyst and aqueous H2O2 oxidant in water, leads to N-oxidation of aliphatic tert-amines to amine N-oxides in quantitative yields, at a high rate at room temperature.

引用

页码：1736 / 1737

页数：2

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