Interaction of Inorganic Nanoparticles with Graphene

被引：72

作者：

Das, Barun ^{[1
,2
,3
]}

Choudhury, Biswajit ^{[1
,2
,6
]}

Gomathi, A. ^{[1
,2
]}

Manna, Arun K. ^{[5
]}

Pati, S. K. ^{[5
]}

Rao, C. N. R. ^{[1
,2
,3
,4
]}

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, New Chem Unit, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

[2] Jawaharlal Nehru Ctr Adv Sci Res, CSIR Ctr Excellence Chem, Bangalore 560064, Karnataka, India

[3] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

[4] Jawaharlal Nehru Ctr Adv Sci Res, Int Ctr Mat Sci, Bangalore 560064, Karnataka, India

[5] Jawaharlal Nehru Ctr Adv Sci Res, Theoret Sci Unit, Bangalore 560064, Karnataka, India

[6] Tezpur Univ, Dept Phys, Napaam 784028, Assam, India

来源：

CHEMPHYSCHEM | 2011年 / 12卷 / 05期

关键词：

charge transfer; doping; graphene; magnetic properties; nanoparticles; MOLECULAR CHARGE-TRANSFER; ELECTRONIC-STRUCTURE; OXIDE; PSEUDOPOTENTIALS; NANOCOMPOSITES; SOLUBILIZATION; SEMICONDUCTOR; DEPOSITION; REDUCTION; CLUSTERS;

D O I：

10.1002/cphc.201001090

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The changes in the electronic and magnetic properties of graphene induced by interaction with semiconducting oxide nanoparticles such as ZnO and TiO2 and with magnetic nanoparticles such as Fe3O4, CoFe2O4, and Ni are investigated by using Raman spectroscopy, magnetic measurements, and first-principles calculations. Significant electronic and magnetic interactions between the nanoparticles and graphene are found. The findings suggest that changes in magnetization as well as the Raman shifts are directly linked to charge transfer between the deposited nanoparticles and graphene. The study thus demonstrates significant effects in tailoring the electronic structure of graphene for applications in futuristic electronic devices.

引用

页码：937 / 943

页数：7

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