Synthesis and structure of (4,4'-H2bpy)[V2(HPO4)4(4,4'-bpy)2], a novel two-dimensional network compound

被引：52

作者：

Huang, CH

Huang, LS

Lii, KH ^{[1
]}

机构：

[1] Natl Cent Univ, Dept Chem, Chungli 320, Taiwan

[2] Acad Sinica, Inst Chem, Taipei 115, Taiwan

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 11期

关键词：

D O I：

10.1021/ic001169g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of the first metal phosphate containing 4,4'-bipyridine in two distinct forms is described; the structure consists of phosphate-bridged vanadium(m) chains, which are linked through 4,4'-bipyridine ligands to form anionic ([V-2(HPO4)(4)- (4,4'-bpy)(2)](2-))(infinity) sheets with the charge-compensating uncoordinated (4,4'-H(2)bpy)(2+) cations between the sheets.

引用

页码：2625 / +

页数：4

共 14 条

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[2]

2-U

[3] Synthesis, crystal structure and 71Ga MAS NMR spectroscopy of a novel gallium phosphatooxalate:: [Ga5(OH)2(C10H9N2)(C2O4)(PO4)4]•2H2O [J].