Diurnal Variability of Pharmaceutical, Personal Care Product, Estrogen and Alkylphenol Concentrations in Effluent from a Tertiary Wastewater Treatment Facility

被引：107

作者：

Nelson, Eric D. ^{[1
]}

Do, Huy ^{[1
]}

Lewis, Roger S. ^{[1
]}

Carr, Steve A. ^{[1
]}

机构：

[1] San Jose Creek Water Qual Lab, Whittier, CA 90601 USA

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 2011年 / 45卷 / 04期

关键词：

TANDEM MASS-SPECTROMETRY; SOLID-PHASE EXTRACTION; SURFACE; FATE; NONYLPHENOL; ETHOXYLATES; OCTYLPHENOL; DISRUPTION; HORMONES;

D O I：

10.1021/es102452f

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Hourly samples of tertiary wastewater effluent were analyzed for 30 pharmaceuticals, personal care products, estrogenic steroids, and alkylphenols in order to better understand the rate at which these compounds enter the environment. Several distinct patterns of daily cycling were observed, and were characterized as three separate categories. The concentrations of compounds such as trimethoprim, sulfamethoxazole, naproxen, estrone, and triclosan varied greatly during a daily cycle, with relative standard deviations exceeding 100% of their daily mean. Less extreme daily cycles were seen for other compounds such as azithromycin, atenolol, tert-octylphenol, iopromide and gemfibrozil. Peak concentrations for most compounds occurred in the early evening (5-8 pm). However, some compounds including carbamazepine, primidone, fluoxetine, and triclocarban exhibited little or no variability.

引用

页码：1228 / 1234

页数：7

共 40 条

[1]

[Anonymous], 2010, 06015 WRF

[2]

[Anonymous], 1998, Issues in Potable Reuse: The Viability ofAugmenting Drinking Water Supplies with Reclaimed Water

[3]

[Anonymous], 2008, 04HHE1CO WAT REUS FD

[4]

[Anonymous], 2008, AP INV PHARM FOUND D

[5]

[Anonymous], 2006, ADV SOIL AQ TREATM R

[6]

Awwa Research Foundation, 2007, REMOVAL EDCS PHARM D

[7] Fate of Sulfamethoxazole, 4-Nonylphenol, and 17β-Estradiol in Groundwater Contaminated by Wastewater Treatment Plant Effluent [J].

Barber, Larry B. ;

Keefe, Steffanie H. ;

Leblanc, Denis R. ;

Bradley, Paul M. ;

Chapelle, Francis H. ;

Meyer, Michael T. ;

Loftin, Keith A. ;

Kolpin, Dana W. ;

Rubio, Fernando .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (13) :4843-4850

[8] Analysis of ecologically relevant pharmaceuticals in wastewater and surface water using selective solid-phase extraction and UPLC-MS/MS [J].

Batt, Angela L. ;

Kostich, Mitch S. ;

Lazorchak, James M. .

ANALYTICAL CHEMISTRY, 2008, 80 (13) :5021-5030

[9] Determination of pharmaceuticals from different therapeutic classes in wastewaters by liquid chromatography-electrospray ionization-tandem mass spectrometry [J].

Botitsi, Eleni ;

Frosyni, Charalampia ;

Tsipi, Despina .

ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2007, 387 (04) :1317-1327

[10] Derivation of an aquatic predicted no-effect concentration for the synthetic hormone, 17α-ethinyl estradiol [J].

Caldwell, Daniel J. ;

Mastrocco, Frank ;

Hutchinson, Thomas H. ;

Laenge, Reinhard ;

Heijerick, Dagobert ;

Janssen, Colin ;

Anderson, Paul D. ;

Sumpter, John P. .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (19) :7046-7054

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