Preparation of biodiesel from crude oil of Pongamia pinnata

被引：437

作者：

Karmee, SK ^{[1
]}

Chadha, A ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Biotechnol, Bioorgan Chem Lab, Madras 600036, Tamil Nadu, India

来源：

BIORESOURCE TECHNOLOGY | 2005年 / 96卷 / 13期

关键词：

Pongamia pinnata; biodiesel; non-edible oil; base catalyst; solid acids; transesterification;

D O I：

10.1016/j.biortech.2004.12.011

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

Biodiesel was prepared from the non-edible oil of Pongamia pinnata by transesterification of the crude oil with methanol in the presence of KOH as catalyst. A maximum conversion of 92% (oil to ester) was achieved using a 1: 10 molar ratio of oil to methanol at 60 degrees C. Tetrahydrofuran (THF), when used as a co-solvent increased the conversion to 95%. Solid acid catalysts viz. HP-Zeolite, Montmorillonite K-10 and ZnO were also used for this transesterification. Important fuel properties of methyl esters of Pongamia oil (Biodiesel) compare well (Viscosity = 4.8 Cst @ 40 degrees C and Flash point = 150 degrees C) with ASTM and German biodiesel standards. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：1425 / 1429

页数：5

共 22 条

[1] Optimisation of biodiesel production by sunflower oil transesterification [J].

Antolín, G ;

Tinaut, FV ;

Briceño, Y ;

Castaño, V ;

Pérez, C ;

Ramírez, AI .

BIORESOURCE TECHNOLOGY, 2002, 83 (02) :111-114

[2] Fast one-phase oil-rich processes for the preparation of vegetable oil methyl esters [J].

Boocock, DGB ;

Konar, SK ;

Mao, V ;

Sidi, H .

BIOMASS & BIOENERGY, 1996, 11 (01) :43-50

[3] Continuous production of palm methyl esters [J].

Darnoko, D ;

Cheryan, M .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2000, 77 (12) :1269-1272

[4] Kinetics of palm oil transesterification in a batch reactor [J].

Darnoko, D ;

Cheryan, M .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2000, 77 (12) :1263-1267

[5] Jatropha curcas L as a source for the production of biofuel in Nicaragua [J].

Foidl, N ;

Foidl, G ;

Sanchez, M ;

Mittelbach, M ;

Hackel, S .

BIORESOURCE TECHNOLOGY, 1996, 58 (01) :77-82

[6] VARIABLES AFFECTING THE YIELDS OF FATTY ESTERS FROM TRANSESTERIFIED VEGETABLE-OILS [J].

FREEDMAN, B ;

PRYDE, EH ;

MOUNTS, TL .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1984, 61 (10) :1638-1643

[7]

FREEDMAN B, 1986, J AM OIL CHEM SOC, V63, P1357

[8] Kinetic study of the base-catalyzed transesterification of monoglycerides from Pongamia oil [J].

Karmee, SK ;

Mahesh, P ;

Ravi, R ;

Chadha, A .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2004, 81 (05) :425-430

[9] Monitoring a progressing transesterification reaction by fiber-optic near infrared spectroscopy with correlation to 1H nuclear magnetic resonance spectroscopy [J].

Knothe, G .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2000, 77 (05) :489-493

[10] Immobilized Candida antarctica lipase-catalyzed alcoholysis of cotton seed oil in a solvent-free medium [J].

Köse, Ö ;

Tüter, M ;

Aksoy, HA .

BIORESOURCE TECHNOLOGY, 2002, 83 (02) :125-129

← 1 2 3 →