Theoretical examination of reference electrodes for lithium-ion cells

被引：68

作者：

Dees, Dennis W. ^{[1
]}

Jansen, Andrew N. ^{[1
]}

Abraham, Daniel P. ^{[1
]}

机构：

[1] Argonne Natl Lab, Argonne, IL 60439 USA

来源：

JOURNAL OF POWER SOURCES | 2007年 / 174卷 / 02期

关键词：

lithium; battery; electrochemical; reference; modeling;

D O I：

10.1016/j.jpowsour.2007.06.128

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An electrochemical model was developed to compare the use of internal and external reference electrodes for the study of lithium-ion cells. The impact of reference electrode placement on electrode measurements was examined using idealized reference electrodes in cells undergoing short-duration pulse currents. The effectiveness of internal reference electrodes with finite size and impedance was also examined. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：1001 / 1006

页数：6

共 13 条

[1] Application of a lithium-tin reference electrode to determine electrode contributions to impedance rise in high-power lithium-ion cells [J].