Photoreversible optical nonlinearities of polymeric films containing spiropyran with long alkyl chains

被引:38
作者
Tamaoki, N [1 ]
VanKeuren, E [1 ]
Matsuda, H [1 ]
Hasegawa, K [1 ]
Yamaoka, T [1 ]
机构
[1] CHIBA UNIV, DEPT IMAGE SCI & TECHNOL, INAGE, CHIBA 263, JAPAN
关键词
D O I
10.1063/1.117406
中图分类号
O59 [应用物理学];
学科分类号
摘要
It was demonstrated that the third-order optical nonlinearity of polymer films could be reversibly controlled by the photochromic conversion and following J-aggregate formation of spiropyr;tn embedded in an inert polymer matrix. Patterns consisting of areas with high and low third-order nonlinear optical activities were prepared by imagewise exposure of the photochromic films followed by thermal treatment to form thermally stable J aggregates of photoinduced merocyanine in the exposed area. This system could be useful in developing new unconventional optical devices based on optical nonlinearities, including new types of spatial light modulators. (C) 1996 American Institute of Physics.
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页码:1188 / 1190
页数:3
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