Morphology evolution of a liquid crystalline polymer confined by highly packed glass beads in polycarbonate

被引：13

作者：

Chen, P

Zhang, J

He, JS ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, Key Lab Engn Plast, Beijing 100080, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

POLYMER | 2005年 / 46卷 / 18期

关键词：

hybrid composites; LCP; morphology;

D O I：

10.1016/j.polymer.2005.05.123

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Very long and perfectly oriented fibrils of a liquid crystalline polymer (LCP) were in situ formed in capillary flows by adding large amounts of glass beads (GB) to a polycarbonate (PC)/LCP blend. Thermodynamically the different interfacial tensions between the components made GB migrate to the LCP phase. Then the high content of GB spheres produced a confined condition, so that the LCP droplets passed through the simultaneously formed inicro-capillaries, followed by being stretched into fibrils and stabilized consequently. (c) 2005 Elsevier Ltd. All rights reserved.

引用

收藏

页码：7652 / 7657

页数：6

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