Theory of enantiomeric control in dimethylallene using achiral light

被引：51

作者：

Gerbasi, D ^{[1
]}

Shapiro, M

Brumer, P

机构：

[1] Univ Toronto, Dept Chem, Chem Phys Theory Grp, Toronto, ON M5S 3H6, Canada

[2] Weizmann Inst Sci, Dept Chem Phys, IL-76100 Rehovot, Israel

来源：

JOURNAL OF CHEMICAL PHYSICS | 2001年 / 115卷 / 12期

关键词：

D O I：

10.1063/1.1405116

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Extensive control over enantiomer populations using achiral light is computationally demonstrated for J, M-J-selected 1,3 dimethylallene. In particular, by altering the detuning of one of three lasers incident on an J, M-J-polarized racemic mixture, one can alter the enantiomeric excess from approximate to 93% of the L enantiomer to approximate to 93% of the D enantiomer. (C) 2001 American Institute of Physics.

引用

页码：5349 / 5352

页数：4

共 16 条

[1] BRUMER P, UNPUB J CHEM PHYS
[2] ON THE PREPARATION AND MEASUREMENT OF SUPERPOSITIONS OF CHIRAL AMPLITUDES
CINA, JA
HARRIS, RA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (04) : 2531 - 2536
[3] A NOVEL DISCRETE VARIABLE REPRESENTATION FOR QUANTUM-MECHANICAL REACTIVE SCATTERING VIA THE S-MATRIX KOHN METHOD
COLBERT, DT
MILLER, WH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (03) : 1982 - 1991
[4] DERETEY E, UNPUB J PHYS CHEM
[5] Fujimura Y, 1999, CHEM PHYS LETT, V310, P578
[6] Selective preparation of enantiomers by laser pulses:: quantum model simulation for H2POSH
Fujimura, Y
González, L
Hoki, K
Manz, J
Ohtsuki, Y
[J]. CHEMICAL PHYSICS LETTERS, 1999, 306 (1-2) : 1 - 8
[7] Fujimura Y, 2000, ANGEW CHEM INT EDIT, V39, P4586, DOI 10.1002/1521-3773(20001215)39:24<4586::AID-ANIE4586>3.0.CO
[8] 2-H
[9] Selective preparation of enantiomers from a racemate by laser pulses:: model simulation for oriented atropisomers with coupled rotations and torsions
Hoki, K
Kröner, D
Manz, J
[J]. CHEMICAL PHYSICS, 2001, 267 (1-3) : 59 - 79
[10] Locally designed pulse shaping for selective preparation of enantiomers from their racemate
Hoki, K
Otsuki, Y
Fujimura, Y
[J]. JOURNAL OF CHEMICAL PHYSICS, 2001, 114 (04) : 1575 - 1581

← 1 2 →