Hexaaquamanganese(II) 3-carboxy-4-hydroxybenzenesulfonate dihydrate

被引：20

作者：

Ma, JF ^{[1
]}

Yang, J ^{[1
]}

Liu, JF ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803013059

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Mn(H2O)(6)]L-2.2H(2)O, where HL is 3-carboxy-4-hydroxybenzenesulfonic acid (C7H6O6S), each Mn-II cation lies on an inversion center and is octahedrally coordinated by six water molecules. The L. anions do not coordinate to manganese, but act as counter-anions. The crystal structure is composed of alternating layers of [Mn(H2O)(6)](2+) cations and sulfonate anions. The [Mn(H2O)(6)](2+) cations, water molecules and L. anions are connected through a complex pattern of H-bonding interactions.

引用

页码：M478 / M480

页数：3

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