A Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides

被引：450

作者：

Federsel, Christopher ^{[2
]}

Boddien, Albert ^{[1
,2
]}

Jackstell, Ralf ^{[2
]}

Jennerjahn, Reiko ^{[2
]}

Dyson, Paul J. ^{[1
]}

Scopelliti, Rosario ^{[1
]}

Laurenczy, Gabor ^{[1
]}

Beller, Matthias ^{[2
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

[2] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 50期

基金：

瑞士国家科学基金会;

关键词：

carbon dioxide; formate; homogeneous catalysis; hydrogenation; iron; HOMOGENEOUS HYDROGENATION; FORMIC-ACID; DIHYDROGEN; COMPLEXES; EFFICIENT; CO2; HYDROSILYLATION; CONVERSION; DIHYDRIDE; LIGAND;

D O I：

10.1002/anie.201004263

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A will of iron: An active well-defined iron complex (see structure; gray C, white H, yellow B, green F, brown Fe, pink P) catalyzes the title reaction (see scheme). The iron-catalyzed reduction of readily available bicarbonates to formates has also been demonstrated for the first time. This reaction could be an important step in the use of CO2 for hydrogen storage. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9777 / 9780

页数：4

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