Redox mediation enabled by immobilised centres in the pores of a metal-organic framework grown by liquid phase epitaxy

被引：92

作者：

Dragaesser, Andre ^{[2
]}

Shekhah, Osama ^{[1
]}

Zybaylo, Olexandra ^{[1
]}

Shen, Cai ^{[3
]}

Buck, Manfred ^{[3
]}

Woell, Christof ^{[1
]}

Schlettwein, Derck ^{[2
]}

机构：

[1] Karlsruhe Inst Technol, Inst Funct Interfaces IFG, D-76344 Eggenstein Leopoldshafen, Germany

[2] Univ Giessen, Inst Appl Phys, D-35392 Giessen, Germany

[3] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 05期

关键词：

COORDINATION POLYMERS; ELECTRON-TRANSFER; CHEMISTRY; IODINE;

D O I：

10.1039/c1cc16580a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A layer of a metal-organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

引用

页码：663 / 665

页数：3

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