Electric field effect on BiFeO3 single crystal investigated by Raman spectroscopy

被引:102
作者
Cazayous, M. [1 ]
Malka, D.
Lebeugle, D.
Colson, D.
机构
[1] Univ Paris Diderot Paris 7, LAb Mat & Phenomenes Quant, UMR 7162, F-75205 Paris 13, France
[2] Ecole Super Phys & Chim Ind Ville Paris, Phys Solides Lab, UPR5, CNRS, F-75231 Paris, France
[3] CEA Saclay, DSM, DRECAM, Serv Phys Etat Condense,SPEC, F-91191 Gif Sur Yvette, France
关键词
D O I
10.1063/1.2771380
中图分类号
O59 [应用物理学];
学科分类号
摘要
Micro-Raman spectroscopy has been used to study lattice dynamics associated with the ferroelectric domains of a BiFeO3 single crystal at low temperature. The phonon assignment shows a large frequency splitting between the transverse and longitudinal components of the A(1) phonon mode related to the Bi-O bonds in contrast with thin films where the splitting is negligible. Applying an external electric field induces frequency shifts of the low energy modes related to the Bi-O bonds. These softenings are due to a tensile stress via the piezoelectric effect. The authors give estimates of the phonon deformation potentials. (C) 2007 American Institute of Physics.
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页数:3
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