Catalyst performance in reforming of tar derived from biomass over noble metal catalysts

被引:69
作者
Tomishige, K [1 ]
Miyazawa, T [1 ]
Asadullah, M [1 ]
Ito, S [1 ]
Kunimori, K [1 ]
机构
[1] Univ Tsukuba, Inst Mat Sci, Tsukuba, Ibaraki 3058573, Japan
关键词
D O I
10.1039/b303371f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An activity test in the reforming of tar derived from cedar biomass over M-CeO2-SiO2 (M = Rh, Pt, Pd, Ru, Ni) was carried out in a secondary fluidized catalyst bed at lower temperature range (823-923 K) than the conventional methods. We have measured the formation rate of CO, CO2, CH4, H-2, and the yield of coke deposited on the catalyst surface and the yield of char accumulated in the primary bed. It was found that Rh-CeO2-SiO2 exhibited much higher performance than other metal catalysts in terms of the activity of tar reforming, and the yield of gas and coke.
引用
收藏
页码:399 / 403
页数:5
相关论文
共 45 条
[1]   The development of a draft protocol for the sampling and analysis of particulate and organic contaminants in the gas from small biomass gasifiers [J].
Abatzoglou, N ;
Barker, N ;
Hasler, P ;
Knoef, H .
BIOMASS & BIOENERGY, 2000, 18 (01) :5-17
[2]  
ABATZOGLOU N, 1997, P 3 BIOM C AM, P599
[3]  
[Anonymous], 1997, DEV THERMOCHEM BIOMA, DOI DOI 10.1007/978-94-009-1559-6_96
[4]   A NEW CATALYST FOR THE CATALYTIC GASIFICATION OF BIOMASS [J].
ARAUZO, J ;
RADLEIN, D ;
PISKORZ, J ;
SCOTT, DS .
ENERGY & FUELS, 1994, 8 (06) :1192-1196
[5]   Catalytic pyrogasification of biomass. Evaluation of modified nickel catalysts [J].
Arauzo, J ;
Radlein, D ;
Piskorz, J ;
Scott, DS .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (01) :67-75
[6]   Energy efficient production of hydrogen and syngas from biomass: Development of low-temperature catalytic process for cellulose gasification [J].
Asadullah, M ;
Ito, SI ;
Kunimori, K ;
Yamada, M ;
Tomishige, K .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (20) :4476-4481
[7]   Role of catalyst and its fluidization in the catalytic gasification of biomass to syngas at low temperature [J].
Asadullah, M ;
Ito, S ;
Kunimori, K ;
Tomishige, K .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (18) :4567-4575
[8]   Biomass gasification to hydrogen and syngas at low temperature: Novel catalytic system using fluidized-bed reactor [J].
Asadullah, M ;
Ito, S ;
Kunimori, K ;
Yamada, M ;
Tomishige, K .
JOURNAL OF CATALYSIS, 2002, 208 (02) :255-259
[9]   Novel biomass gasification method with high efficiency: catalytic gasification at low temperature [J].
Asadullah, M ;
Miyazawa, T ;
Ito, S ;
Kunimori, K ;
Yamada, M ;
Tomishige, K .
GREEN CHEMISTRY, 2002, 4 (04) :385-389
[10]   Catalytic performance of Rh/CeO2 in the gasification of cellulose to synthesis gas at low temperature [J].
Asadullah, M ;
Fujimoto, K ;
Tomishige, K .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (25) :5894-5900