Synthesis, structural characterization, and luminescence properties of branched palladium(II) and platinum(II) acetylide complexes

被引：89

作者：

Yam, VWW ^{[1
]}

Tao, CH ^{[1
]}

Zhang, LJ ^{[1
]}

Wong, KMC ^{[1
]}

Cheung, KK ^{[1
]}

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 03期

关键词：

D O I：

10.1021/om000821c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three luminescent palladium(II) and platinum(II) acetylide complexes, 1,3-[Cl(PEt3)(2)PdC=CC6H4C=C](2)-5-[(Pr-i)(3)SiC=C]C6H3 and 1,3,5-[Cl(PEt3)(2)MC=CC6H4C=C](3)C6H3 (M = Pd or Pt), have been synthesized by the reaction of the corresponding starting complexes, trans-M(PEt3)(2)Cl-2 (M = Pd or Pt), with branched alkynyl ligands. Their crystal structures, together with their luminescence behavior, have been reported.

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页码：453 / 459

页数：7

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